1,3-Dioxane-4-carboxaldehyde, 5-hydroxy-2-methyl-, (2S,4S,5R)-

Base Information

Chemical Name:1,3-Dioxane-4-carboxaldehyde, 5-hydroxy-2-methyl-, (2S,4S,5R)-
CAS No.:87068-62-0
Molecular Formula:C6H10O4
Molecular Weight:146.14100
Hs Code.:
DSSTox Substance ID:DTXSID40473976
Nikkaji Number:J1.133.898D
Wikidata:Q82303699
Mol file:87068-62-0.mol

Synonyms:87068-62-0;1,3-Dioxane-4-carboxaldehyde, 5-hydroxy-2-methyl-, (2S,4S,5R)-;DTXSID40473976

Suppliers and Price of 1,3-Dioxane-4-carboxaldehyde, 5-hydroxy-2-methyl-, (2S,4S,5R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 1,3-Dioxane-4-carboxaldehyde, 5-hydroxy-2-methyl-, (2S,4S,5R)-

Chemical Property:

PSA：55.76000
LogP:-0.69240
XLogP3:-0.3
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:1
Exact Mass:146.05790880
Heavy Atom Count:10
Complexity:125

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1OCC(C(O1)C=O)O
Isomeric SMILES:C[C@H]1OC[C@H]([C@H](O1)C=O)O

Technology Process of 1,3-Dioxane-4-carboxaldehyde, 5-hydroxy-2-methyl-, (2S,4S,5R)-

There total 1 articles about 1,3-Dioxane-4-carboxaldehyde, 5-hydroxy-2-methyl-, (2S,4S,5R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 112246-57-8
O⁴,O⁶-((S)-ethylidene)-L-glucose

: 24871-55-4,70377-89-8,87068-62-0,315216-23-0
O²,O⁴-((S)-ethyliden)-L-erythrose

Guidance literature:: With sodium periodate; water; sodium hydrogencarbonate;
DOI:10.1021/ja01156a002

Reference yield: 73.0%

: 29601-98-7
N-benzylhydroxylamine hydrochloride

: 87068-62-0,315216-23-0
2,4-O-(1S)-ethylidene-D-threose

: 204759-79-5,575450-68-9
(Z)-N-(1-deoxy-2,4-O-ethylidene-D-threo-1-ylidene)benzylamine N-oxide

Guidance literature:: With 2-Pyridone; magnesium sulfate; In dichloromethane; at 20 ℃; for 16h;
DOI:10.1016/S0040-4020(99)00512-8

Reference yield:

: 87068-62-0,315216-23-0
2,4-O-(1S)-ethylidene-D-threose

: (3R,5S,2'S,4'R,5'R)-3-(5'-hydroxy-2'-methyl-1',3'-dioxanyl)-2-benzyl-5-phenylisoxazolidine

Guidance literature:: Multi-step reaction with 2 steps

1: 73 percent / 2-pyridone; MgSO₄ / CH₂Cl₂ / 16 h / 20 °C

2: toluene / 10 h / 110 °C

With 2-Pyridone; magnesium sulfate; In dichloromethane; toluene; 1: Condensation / 2: Cycloaddition;
DOI:10.1016/S0040-4020(99)00512-8