Technology Process of Germane, (trifluoromethyl)-
There total 3 articles about Germane, (trifluoromethyl)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
H3PO4; NaBD4;
In
water;
30% H3PO4 placed in a flask and attached to a vacuum line via a reflux condenser kept at -20°C, addn. (CF3)GeI3 to ice-cooled acid, soln. NaBD4/H2O added over 1h (pressure maintained at 600 mbar), evolved gases collected (2 traps, -196°C); fractional condensation, isothermal distn. at 0°C (slit tube column), not isolated, detected by NMR-spect.;
DOI:10.1016/0022-328X(86)84031-1
- Guidance literature:
-
In
N,N,N,N,N,N-hexamethylphosphoric triamide;
twofold excess of CF3Br; 0°C, 2 min;
DOI:10.1063/1.1682510
- Guidance literature:
-
With
H3PO4; NaBH4;
In
water;
30% H3PO4 placed in a flask and attached to a vacuum line via a reflux condenser kept at -20°C, addn. (CF3)GeI3 to ice-cooled acid, soln. NaBH4/H2O added over 1h (pressure maintained at 600 mbar), evolved gases collected (2 traps, -196°C); fractional condensation, isothermal distn. at 0°C (slit tube column);
DOI:10.1016/0022-328X(86)84031-1
