Silane, (1,1-dimethylethyl)diphenyl[[(2R,3R,6S)-tetrahydro-3-methyl-6-[(1E,3S)- 3-[(2R,3S,5R)-tetrahydro-5-[(1S)-1-methoxyethyl]-3-methyl-2-furanyl]-1- butenyl]-2H-pyran-2-yl]methoxy]-

Base Information

Chemical Name:Silane, (1,1-dimethylethyl)diphenyl[[(2R,3R,6S)-tetrahydro-3-methyl-6-[(1E,3S)- 3-[(2R,3S,5R)-tetrahydro-5-[(1S)-1-methoxyethyl]-3-methyl-2-furanyl]-1- butenyl]-2H-pyran-2-yl]methoxy]-
CAS No.:876152-50-0
Molecular Formula:C35H52O4Si
Molecular Weight:564.881
Hs Code.:

Silane,
(1,1-dimethylethyl)diphenyl[[(2R,3R,6S)-tetrahydro-3-methyl-6-[(1E,3S)-
3-[(2R,3S,5R)-tetrahydro-5-[(1S)-1-methoxyethyl]-3-methyl-2-furanyl]-1-
butenyl]-2H-pyran-2-yl]methoxy]-

Synonyms:

Suppliers and Price of Silane, (1,1-dimethylethyl)diphenyl[[(2R,3R,6S)-tetrahydro-3-methyl-6-[(1E,3S)- 3-[(2R,3S,5R)-tetrahydro-5-[(1S)-1-methoxyethyl]-3-methyl-2-furanyl]-1- butenyl]-2H-pyran-2-yl]methoxy]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Silane, (1,1-dimethylethyl)diphenyl[[(2R,3R,6S)-tetrahydro-3-methyl-6-[(1E,3S)- 3-[(2R,3S,5R)-tetrahydro-5-[(1S)-1-methoxyethyl]-3-methyl-2-furanyl]-1- butenyl]-2H-pyran-2-yl]methoxy]-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Silane, (1,1-dimethylethyl)diphenyl[[(2R,3R,6S)-tetrahydro-3-methyl-6-[(1E,3S)- 3-[(2R,3S,5R)-tetrahydro-5-[(1S)-1-methoxyethyl]-3-methyl-2-furanyl]-1- butenyl]-2H-pyran-2-yl]methoxy]-

There total 14 articles about Silane, (1,1-dimethylethyl)diphenyl[[(2R,3R,6S)-tetrahydro-3-methyl-6-[(1E,3S)- 3-[(2R,3S,5R)-tetrahydro-5-[(1S)-1-methoxyethyl]-3-methyl-2-furanyl]-1- butenyl]-2H-pyran-2-yl]methoxy]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 27610-27-1,105814-63-9
5-(1-hydroxyethyl)dihydrofuran-2(3H)-one

: 876152-50-0
tert-Butyl-((2R,3R,6S)-6-{(E)-(S)-3-[(2R,3S,5R)-5-((S)-1-methoxy-ethyl)-3-methyl-tetrahydro-furan-2-yl]-but-1-enyl}-3-methyl-tetrahydro-pyran-2-ylmethoxy)-diphenyl-silane

Guidance literature:: Multi-step reaction with 9 steps

1.1: 70 percent / DIAD; PPh₃ / toluene / 16 h / 20 °C

2.1: 94 percent / KOH / ethanol / 2 h / 60 °C

3.1: 77 percent / imidazole / CH₂Cl₂ / 16 h / 20 °C

4.1: LDA / tetrahydrofuran / 2 h / -78 °C

4.2: tetrahydrofuran / 2 h / -78 °C

5.1: DIBAL-H / CH₂Cl₂ / 1 h / -78 °C

6.1: BF₃*OEt₂ / CH₂Cl₂ / 1 h / -78 °C

7.1: TBAF / tetrahydrofuran / 16 h / 20 °C

8.1: 81 percent / NaH / dimethylformamide / 2 h / 20 °C

With 1H-imidazole; potassium hydroxide; di-isopropyl azodicarboxylate; boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; sodium hydride; diisobutylaluminium hydride; triphenylphosphine; lithium diisopropyl amide; In tetrahydrofuran; ethanol; dichloromethane; N,N-dimethyl-formamide; toluene; 1.1: Mitsunobu reaction;
DOI:10.1055/s-2005-918486

Reference yield:

: 876152-48-6
(S)-1-((2R,4S)-4-Methyl-5-phenylsulfanyl-tetrahydro-furan-2-yl)-ethanol

: 876152-50-0
tert-Butyl-((2R,3R,6S)-6-{(E)-(S)-3-[(2R,3S,5R)-5-((S)-1-methoxy-ethyl)-3-methyl-tetrahydro-furan-2-yl]-but-1-enyl}-3-methyl-tetrahydro-pyran-2-ylmethoxy)-diphenyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: 81 percent / NaH / dimethylformamide / 2 h / 20 °C

With sodium hydride; In N,N-dimethyl-formamide;
DOI:10.1055/s-2005-918486

Reference yield:

: 876152-46-4
(E)-(R)-4-((2S,5R,6R)-6-Hydroxymethyl-5-methyl-tetrahydro-pyran-2-yl)-but-3-en-2-ol

: 876152-50-0
tert-Butyl-((2R,3R,6S)-6-{(E)-(S)-3-[(2R,3S,5R)-5-((S)-1-methoxy-ethyl)-3-methyl-tetrahydro-furan-2-yl]-but-1-enyl}-3-methyl-tetrahydro-pyran-2-ylmethoxy)-diphenyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1: 49 percent / imidazole / CH₂Cl₂ / 16 h / 20 °C

2: 90 percent / DMAP / CH₂Cl₂ / 16 h / 20 °C

With 1H-imidazole; dmap; In dichloromethane;
DOI:10.1055/s-2005-918486