Oxacyclotetradec-3-en-2-one, 5,6,8-trihydroxy-14-pentyl-, (3E)-

Base Information

Chemical Name:Oxacyclotetradec-3-en-2-one, 5,6,8-trihydroxy-14-pentyl-, (3E)-
CAS No.:877061-66-0
Molecular Formula:C₁₈H₃₂O₅
Molecular Weight:328.449
Hs Code.:

Synonyms:

Suppliers and Price of Oxacyclotetradec-3-en-2-one, 5,6,8-trihydroxy-14-pentyl-, (3E)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 4 raw suppliers

Chemical Property of Oxacyclotetradec-3-en-2-one, 5,6,8-trihydroxy-14-pentyl-, (3E)-

Chemical Property:

Purity/Quality:: >95% by HPLC ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Oxacyclotetradec-3-en-2-one, 5,6,8-trihydroxy-14-pentyl-, (3E)-

There total 88 articles about Oxacyclotetradec-3-en-2-one, 5,6,8-trihydroxy-14-pentyl-, (3E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: (5R,6S,8R,14R,E)-5,6,8-tris[(tert-butyldimethylsilyl)oxy]-14-pentyl oxacyclotetradec-3-en-2-one

: 877061-66-0
(5R,6S,8R,14R,E)-5,6,8-trihydroxy-14-pentyloxacyclotetradec-3-en-2-one

Guidance literature:: With hydrogen fluoride; In dichloromethane; water; acetonitrile; at 20 ℃; for 3h; regioselective reaction;
DOI:10.1002/anie.201608406

Reference yield: 89.0%

: (3aR,8R,14R,15aS,E)-14-hydroxy-2,2-dimethyl-8-pentyl-9,10,11,12,13,14,15,15a-octahydro-3aH-[1,3]dioxolo[4,5-e][1]-oxacyclotetradecin-6(8H)-one

: 877061-66-0
(5R,6S,8R,14R,E)-5,6,8-trihydroxy-14-pentyloxacyclotetradec-3-en-2-one

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; water; at 20 ℃; for 4h; Inert atmosphere;
DOI:10.1021/acs.joc.5b02318

Reference yield: 84.0%

: (6R,12R,14S,15R)-12,14,15-tris(methoxymethoxy)heptadec-16-en-6-yl acrylate

: 877061-66-0
(5R,6S,8R,14R,E)-5,6,8-trihydroxy-14-pentyloxacyclotetradec-3-en-2-one

Guidance literature:: (6R,12R,14S,15R)-12,14,15-tris(methoxymethoxy)heptadec-16-en-6-yl acrylate; With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; for 6h; Inert atmosphere; Reflux;

With trifluoroacetic acid; In dichloromethane; at 20 ℃; for 36h; Inert atmosphere;
DOI:10.1021/acs.orglett.5b03547