(1S,5S)-3-oxabicyclo[3.3.0]oct-6-en-2-one

Base Information

Chemical Name:(1S,5S)-3-oxabicyclo[3.3.0]oct-6-en-2-one
CAS No.:77189-14-1
Molecular Formula:C₇H₈O₂
Molecular Weight:124.139
Hs Code.:
Mol file:77189-14-1.mol

Synonyms:1H-Cyclopenta[c]furan-1-one,3,3a,6,6a-tetrahydro-, cis-; (3aR,6aS)-rel-3,3a,6,6a-Tetrahydro-1H-cyclopenta[c]furan-1-one;NSC 362077

Suppliers and Price of (1S,5S)-3-oxabicyclo[3.3.0]oct-6-en-2-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 10 raw suppliers

Chemical Property of (1S,5S)-3-oxabicyclo[3.3.0]oct-6-en-2-one

Chemical Property:

Vapor Pressure:0.0105mmHg at 25°C
Boiling Point:263.1°C at 760 mmHg
Flash Point:104°C
PSA：26.30000
Density:1.196g/cm³
LogP:0.73550

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (1S,5S)-3-oxabicyclo[3.3.0]oct-6-en-2-one

There total 9 articles about (1S,5S)-3-oxabicyclo[3.3.0]oct-6-en-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: methyl cis-2-bromomethyl-3-cyclopentenyl-1-carboxylate

: 77189-14-1,84899-17-2,103618-27-5,128946-78-1
1-oxo-1,3,3a,6a-tetrahydrocyclopentafuran

Guidance literature:: With silver nitrate; In tetrahydrofuran; water; for 1h; Ambient temperature;
DOI:10.1002/hlca.19820650742

Reference yield: 83.0%

: 13173-09-6,62182-73-4,71155-04-9,71155-05-0
bicyclo[3.2.0]hept-2-en-6-one

: 26054-46-6
cis-(±)-2-oxabicyclo[3.3.0]oct-6-en-3-one

: 77189-14-1,84899-17-2,103618-27-5,128946-78-1
1-oxo-1,3,3a,6a-tetrahydrocyclopentafuran

Guidance literature:: With lithium(etherate)2.5 tetrakis(pentafluorophenyl)borate; dihydrogen peroxide; oxalic acid; In 1,2-dichloro-ethane; at 20 ℃; for 1h; Reagent/catalyst; Time; regioselective reaction; Catalytic behavior;
DOI:10.1002/anie.201204286