Tuliposide A

Base Information

Chemical Name:Tuliposide A
CAS No.:19870-30-5
Molecular Formula:C₁₁H₁₈O₈
Molecular Weight:278.259
Hs Code.:
DSSTox Substance ID:DTXSID20941709
Nikkaji Number:J15.502K
Wikidata:Q27108493
Metabolomics Workbench ID:68093
ChEMBL ID:CHEMBL1255769
Mol file:19870-30-5.mol

Synonyms:1-tuliposide A;tuliposide A

Suppliers and Price of Tuliposide A

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Tuliposide A

Chemical Property:

Vapor Pressure:1.23E-13mmHg at 25°C
Boiling Point:534.1°Cat760mmHg
PKA:12.51±0.70(Predicted)
Flash Point:206°C
PSA：136.68000
Density:1.48g/cm³
LogP:-2.73190
XLogP3:-1.8
Hydrogen Bond Donor Count:5
Hydrogen Bond Acceptor Count:8
Rotatable Bond Count:6
Exact Mass:278.10016753
Heavy Atom Count:19
Complexity:331

Purity/Quality:: >95% by HPLC ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Chemical Classes:Biological Agents -> Plant-Derived Allergens
Canonical SMILES:C=C(CCO)C(=O)OC1C(C(C(C(O1)CO)O)O)O
Isomeric SMILES:C=C(CCO)C(=O)O[C@H]1[C@@H]([C@H]([C@@H]([C@H](O1)CO)O)O)O
Description Tuliposide is a prohapten contained in tulip bulbs and in alstroemerias (Tulipa spp.; Alstroemeria spp.; Lilium spp.). It is rapidly hydrolyzed to Tulipalin A and represents a common occupational problem among workers in the European tulip industry.

Technology Process of Tuliposide A

There total 5 articles about Tuliposide A which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 86762-86-9
4-Hydroxy-2-methylene-butyric acid (2S,3R,4S,5R,6R)-3,4,5-tris-(2,2,2-trifluoro-acetoxy)-6-(2,2,2-trifluoro-acetoxymethyl)-tetrahydro-pyran-2-yl ester

: 19870-30-5
tuliposide-A

Guidance literature:: With CH₃OH,Amberlite-IRA-400(HCO₃^-); for 0.0833333h; or in acetone through a short alumina column;
DOI:10.1016/S0040-4039(00)88020-X

Reference yield:

: 86762-84-7
silver γ-hydroxy-α-methylene-butyrate

: 19870-30-5
tuliposide-A

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / benzene / 168 h / Ambient temperature

2: 83 percent / CH₃OH,Amberlite-IRA-400(HCO₃^-) / 0.08 h / or in acetone through a short alumina column

With CH₃OH,Amberlite-IRA-400(HCO₃^-); In benzene;
DOI:10.1016/S0040-4039(00)88020-X

Reference yield:

: 10548-47-7,14214-12-1
tri-O-TFA-1,6-anhydroglucose

: 19870-30-5
tuliposide-A

Guidance literature:: Multi-step reaction with 3 steps

1: 69 percent / TiBr₄ / 5 h / Heating

2: 87 percent / benzene / 168 h / Ambient temperature

3: 83 percent / CH₃OH,Amberlite-IRA-400(HCO₃^-) / 0.08 h / or in acetone through a short alumina column

With CH₃OH,Amberlite-IRA-400(HCO₃^-); titanium(IV) bromide; In benzene;
DOI:10.1016/S0040-4039(00)88020-X