Octanoic acid, (1S,2E)-2-[2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]ethyl]-1-[2,2-dimethyl- 1-oxo-3-(phenylmethoxy)propyl]-2,4-pentadienyl ester

Base Information

Chemical Name:Octanoic acid, (1S,2E)-2-[2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]ethyl]-1-[2,2-dimethyl- 1-oxo-3-(phenylmethoxy)propyl]-2,4-pentadienyl ester
CAS No.:880343-26-0
Molecular Formula:C33H54O5Si
Molecular Weight:558.874
Hs Code.:

Octanoic acid,
(1S,2E)-2-[2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]ethyl]-1-[2,2-dimethyl-
1-oxo-3-(phenylmethoxy)propyl]-2,4-pentadienyl ester

Synonyms:

Suppliers and Price of Octanoic acid, (1S,2E)-2-[2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]ethyl]-1-[2,2-dimethyl- 1-oxo-3-(phenylmethoxy)propyl]-2,4-pentadienyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Octanoic acid, (1S,2E)-2-[2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]ethyl]-1-[2,2-dimethyl- 1-oxo-3-(phenylmethoxy)propyl]-2,4-pentadienyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Octanoic acid, (1S,2E)-2-[2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]ethyl]-1-[2,2-dimethyl- 1-oxo-3-(phenylmethoxy)propyl]-2,4-pentadienyl ester

There total 4 articles about Octanoic acid, (1S,2E)-2-[2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]ethyl]-1-[2,2-dimethyl- 1-oxo-3-(phenylmethoxy)propyl]-2,4-pentadienyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 880343-25-9
(E)-(S)-1-Benzyloxy-5-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-4-hydroxy-2,2-dimethyl-octa-5,7-dien-3-one

: 124-07-2
Octanoic acid

: 880343-26-0
Octanoic acid (E)-(S)-1-(3-benzyloxy-2,2-dimethyl-propionyl)-2-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-penta-2,4-dienyl ester

Guidance literature:: With dmap; dacarbazine; In dichloromethane; at 25 ℃; for 20h;
DOI:10.1021/ol052976s

Reference yield:

: tert-butyl(hex-5-en-3-yn-1-yloxy)dimethylsilane

: 880343-26-0
Octanoic acid (E)-(S)-1-(3-benzyloxy-2,2-dimethyl-propionyl)-2-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-penta-2,4-dienyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: Ph₃CCO₂H; (R)-Tol-BINAP; H₂ / Rh(COD)2OTf / 1,2-dichloro-ethane / 65 °C / 760 Torr

2: 92 percent / DIC; DMAP / CH₂Cl₂ / 20 h / 25 °C

With dmap; (R)-2,2'-bis[bis(3-methylphenyl)phosphino]-1,1'-binaphthyl; triphenylacetic acid; hydrogen; dacarbazine; bis(cycloocta-1,5-diene)rhodium(I) trifluoromethanesulfonate; In dichloromethane; 1,2-dichloro-ethane;
DOI:10.1021/ol052976s

Reference yield:

: 880343-24-8
4-benzyloxy-3,3-dimethyl-2-oxo-butyraldehyde

: 880343-26-0
Octanoic acid (E)-(S)-1-(3-benzyloxy-2,2-dimethyl-propionyl)-2-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-penta-2,4-dienyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: Ph₃CCO₂H; (R)-Tol-BINAP; H₂ / Rh(COD)2OTf / 1,2-dichloro-ethane / 65 °C / 760 Torr

2: 92 percent / DIC; DMAP / CH₂Cl₂ / 20 h / 25 °C

With dmap; (R)-2,2'-bis[bis(3-methylphenyl)phosphino]-1,1'-binaphthyl; triphenylacetic acid; hydrogen; dacarbazine; bis(cycloocta-1,5-diene)rhodium(I) trifluoromethanesulfonate; In dichloromethane; 1,2-dichloro-ethane;
DOI:10.1021/ol052976s