Technology Process of 2H-1,3,2-Diazagermol-2-ylidene,
1,3-bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-
There total 5 articles about 2H-1,3,2-Diazagermol-2-ylidene,
1,3-bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
B(C6F5)3; 1,3-di-tert-butylimidazol-2-ylidene;
In
toluene;
byproducts: 1,3-di-tert-butylimidazolium HB(C6F5)3; (N2); dropwise addn. of a soln. of carbene in toluene to a stirred soln.of Ge complex in toluene at room temp., dropwise addn. of a soln. of bo ron compd. in toluene, react. for 30 min; evapn. in vac., extn. with n-hexane;
DOI:10.1039/c002395g
- Guidance literature:
-
With
Li; Na;
In
tetrahydrofuran;
Ar; soln. of ligand (1 mmol) in THF treated with Li powder (10 mmol) anda sliver of Na, suspnd. for 3 h, ppt. filtered off, Ge compd. (1 mmol) added to filtrate in 45 min at -78°C, mixt. warmed to room temp., stirred for 16 h; evapd., extd. (hexane), filtered, crystd. (-30°C overnight), elem. anal.;
DOI:10.1016/j.ica.2006.12.014
- Guidance literature:
-
1,2-bis(2,6-diisopropylphenylimino)ethane;
With
lithium;
In
tetrahydrofuran;
Inert atmosphere;
Schlenk technique;
germanium(II) chloride dioxane;
In
tetrahydrofuran;
Inert atmosphere;
Schlenk technique;
DOI:10.1155/2019/9178371
![[(N(2,6-diisopropylphenyl)CH)2]GeH<sub>2</sub>](/Databaselist/images/loading.webp)
