Bicyclo(2.2.1)heptane-2-pentanol, beta,2-dimethyl-3-methylene-

Base Information

Chemical Name:Bicyclo(2.2.1)heptane-2-pentanol, beta,2-dimethyl-3-methylene-
CAS No.:34289-89-9
Deprecated CAS:25992-30-7
Molecular Formula:C15H26O
Molecular Weight:222.3663
Hs Code.:
DSSTox Substance ID:DTXSID60885577
Nikkaji Number:J422.309H
Mol file:34289-89-9.mol

Synonyms:34289-89-9;Bicyclo(2.2.1)heptane-2-pentanol, beta,2-dimethyl-3-methylene-;Bicyclo[2.2.1]heptane-2-pentanol, .beta.,2-dimethyl-3-methylene-;2-(4-Hydroxymethylpentyl)-2-methyl-3-methylenebicyclo(2.2.1)heptane;SCHEMBL11357721;DTXSID60885577;beta,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane-2-(1-pentanol)

Suppliers and Price of Bicyclo(2.2.1)heptane-2-pentanol, beta,2-dimethyl-3-methylene-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Bicyclo(2.2.1)heptane-2-pentanol, beta,2-dimethyl-3-methylene-

Chemical Property:

Vapor Pressure:8.23E-05mmHg at 25°C
Boiling Point:304.6°Cat760mmHg
Flash Point:110.3°C
PSA：20.23000
Density:0.95g/cm³
LogP:3.77750
XLogP3:4.3
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:5
Exact Mass:222.198365449
Heavy Atom Count:16
Complexity:271

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(CCCC1(C2CCC(C2)C1=C)C)CO

Technology Process of Bicyclo(2.2.1)heptane-2-pentanol, beta,2-dimethyl-3-methylene-

There total 6 articles about Bicyclo(2.2.1)heptane-2-pentanol, beta,2-dimethyl-3-methylene- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 27548-52-3,27548-53-4,37402-55-4,69652-68-2,73838-33-2,73838-34-3
(E/Z)-ethyl 2-methyl-5-(2exo-methyl-3-methylidene-bicyclo<2.2.1>hept-2-yl)-2-pentenoate

: 34289-89-9,25992-30-7
dihydroepi-β-santalol

Guidance literature:: With ammonia; lithium; In diethyl ether; ethanol;
DOI:10.1021/jo01303a026

Reference yield:

: 73838-31-0
3-(2exo-methyl-3-methylidene-bicyclo<2.2.1>hept-2-yl)propanal

: 34289-89-9,25992-30-7
dihydroepi-β-santalol

Guidance literature:: Multi-step reaction with 2 steps

1: 1) NaH / 1) DME, 2a) 0 deg C, 2b) 25 deg C, 1h, 2c) 60-70 deg C, 30 min

2: 70 percent / lithium/ammonia / ethanol; diethyl ether

With ammonia; lithium; sodium hydride; In diethyl ether; ethanol;
DOI:10.1021/jo01303a026

Reference yield:

: 69667-88-5
ethyl 3-(2-exo-methyl-3-methylenebicyclo<2.2.1>hept-2-yl)propanoate

: 34289-89-9,25992-30-7
dihydroepi-β-santalol

Guidance literature:: Multi-step reaction with 3 steps

1: diisobutylaluminum hydride / toluene; hexane / 3.5 h / -78 °C

2: 1) NaH / 1) DME, 2a) 0 deg C, 2b) 25 deg C, 1h, 2c) 60-70 deg C, 30 min

3: 70 percent / lithium/ammonia / ethanol; diethyl ether

With ammonia; lithium; sodium hydride; diisobutylaluminium hydride; In diethyl ether; ethanol; hexane; toluene;
DOI:10.1021/jo01303a026