6-Hepten-3-one, 1-[(2R,3R,5S)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-5-[[[(1,1-dimethyl ethyl)diphenylsilyl]oxy]methyl]tetrahydro-2-furanyl]-2-methyl-, (2S)-

Base Information

Chemical Name:6-Hepten-3-one, 1-[(2R,3R,5S)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-5-[[[(1,1-dimethyl ethyl)diphenylsilyl]oxy]methyl]tetrahydro-2-furanyl]-2-methyl-, (2S)-
CAS No.:881651-56-5
Molecular Formula:C35H54O4Si2
Molecular Weight:594.982
Hs Code.:

6-Hepten-3-one,
1-[(2R,3R,5S)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-5-[[[(1,1-dimethyl
ethyl)diphenylsilyl]oxy]methyl]tetrahydro-2-furanyl]-2-methyl-, (2S)-

Synonyms:

Suppliers and Price of 6-Hepten-3-one, 1-[(2R,3R,5S)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-5-[[[(1,1-dimethyl ethyl)diphenylsilyl]oxy]methyl]tetrahydro-2-furanyl]-2-methyl-, (2S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 6-Hepten-3-one, 1-[(2R,3R,5S)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-5-[[[(1,1-dimethyl ethyl)diphenylsilyl]oxy]methyl]tetrahydro-2-furanyl]-2-methyl-, (2S)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 6-Hepten-3-one, 1-[(2R,3R,5S)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-5-[[[(1,1-dimethyl ethyl)diphenylsilyl]oxy]methyl]tetrahydro-2-furanyl]-2-methyl-, (2S)-

There total 11 articles about 6-Hepten-3-one, 1-[(2R,3R,5S)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-5-[[[(1,1-dimethyl ethyl)diphenylsilyl]oxy]methyl]tetrahydro-2-furanyl]-2-methyl-, (2S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 881651-55-4
(S)-1-[(2R,3R,5S)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-2-methyl-hept-6-en-3-ol

: 881651-56-5
(S)-1-[(2R,3R,5S)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-2-methyl-hept-6-en-3-one

Guidance literature:: With Dess-Martin periodane; In dichloromethane; at 0 - 25 ℃; for 4h;
DOI:10.1021/ja054750q

Reference yield:

: 881651-48-5
(E)-(2S,4R,7S)-8-Benzyloxy-7-methyl-oct-5-ene-1,2,4-triol

: 881651-56-5
(S)-1-[(2R,3R,5S)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-2-methyl-hept-6-en-3-one

Guidance literature:: Multi-step reaction with 8 steps

1.1: 70 percent / N-iodosuccinimide; NaHCO₃ / tetrahydrofuran / 36 h / 0 °C

2.1: 99 percent / Et₃N; 4-DMAP / CH₂Cl₂ / 0 - 25 °C

3.1: 100 percent / 2,6-lutidine / CH₂Cl₂ / 0.5 h / 0 °C

4.1: 99 percent / H₂ / Raney-Ni / ethanol / 1 h / 25 °C

5.1: 88 percent / H₂ / Pd(OH)2/C / ethanol / 3 h / 25 °C

6.1: 99 percent / Dess-Martin periodinane / CH₂Cl₂ / 2 h / 0 - 25 °C

7.1: Mg / tetrahydrofuran / 2 h / 25 °C

7.2: tetrahydrofuran / 2 h / -78 - 0 °C

8.1: 40.9 g / Dess-Martin periodinane / CH₂Cl₂ / 4 h / 0 - 25 °C

With 2,6-dimethylpyridine; dmap; N-iodo-succinimide; hydrogen; sodium hydrogencarbonate; Dess-Martin periodane; magnesium; triethylamine; palladium dihydroxide; nickel; In tetrahydrofuran; ethanol; dichloromethane;
DOI:10.1021/ja054750q

Reference yield:

: 881651-50-9
(2S,3R,5S)-2-((1S,2R)-3-Benzyloxy-1-iodo-2-methyl-propyl)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-3-ol

: 881651-56-5
(S)-1-[(2R,3R,5S)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-2-methyl-hept-6-en-3-one

Guidance literature:: Multi-step reaction with 6 steps

1.1: 100 percent / 2,6-lutidine / CH₂Cl₂ / 0.5 h / 0 °C

2.1: 99 percent / H₂ / Raney-Ni / ethanol / 1 h / 25 °C

3.1: 88 percent / H₂ / Pd(OH)2/C / ethanol / 3 h / 25 °C

4.1: 99 percent / Dess-Martin periodinane / CH₂Cl₂ / 2 h / 0 - 25 °C

5.1: Mg / tetrahydrofuran / 2 h / 25 °C

5.2: tetrahydrofuran / 2 h / -78 - 0 °C

6.1: 40.9 g / Dess-Martin periodinane / CH₂Cl₂ / 4 h / 0 - 25 °C

With 2,6-dimethylpyridine; hydrogen; Dess-Martin periodane; magnesium; palladium dihydroxide; nickel; In tetrahydrofuran; ethanol; dichloromethane;
DOI:10.1021/ja054750q