N-methyl-N-[(Z)-[(3E)-3-[methyl(phenyl)hydrazinylidene]butan-2-ylidene]amino]aniline

Base Information

• Chemical Name: N-methyl-N-[(Z)-[(3E)-3-[methyl(phenyl)hydrazinylidene]butan-2-ylidene]amino]aniline
• CAS No.: 42479-40-3
• Molecular Formula: C₁₈H₂₂N₄
• Molecular Weight: 294.399
• NSC Number: 115098
• DSSTox Substance ID: DTXSID30426017
• Wikidata: Q82238990
• Mol file: 42479-40-3.mol

Synonyms:NSC115098;42479-40-3;DTXSID30426017;NSC-115098

Chemical Property of N-methyl-N-[(Z)-[(3E)-3-[methyl(phenyl)hydrazinylidene]butan-2-ylidene]amino]aniline

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Boiling Point: 405.8°Cat760mmHg
• Flash Point: 199.2°C
• Density: 1g/cm³
• XLogP3: 4.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 5
• Exact Mass: 294.18444672
• Heavy Atom Count: 22
• Complexity: 352

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=NN(C)C1=CC=CC=C1)C(=NN(C)C2=CC=CC=C2)C
• Isomeric SMILES: C/C(=N\N(C)C1=CC=CC=C1)/C(=N\N(C)C2=CC=CC=C2)/C

Technology Process of N-methyl-N-[(Z)-[(3E)-3-[methyl(phenyl)hydrazinylidene]butan-2-ylidene]amino]aniline

There total 2 articles about N-methyl-N-[(Z)-[(3E)-3-[methyl(phenyl)hydrazinylidene]butan-2-ylidene]amino]aniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-hydroxy-2-butanon (513-86-0,52217-02-4,51555-24-9) → biacetyl bis(N-methyl-N-phenylhydrazone) (42479-40-3)

Guidance literature:

Reference yield:

dimethylglyoxal (431-03-8) → biacetyl bis(N-methyl-N-phenylhydrazone) (42479-40-3)

Guidance literature:

Reference yield: 74.0%

bis(2,2'-bipyridine)dichlororuthenium(II) dihydrate + biacetyl bis(N-methyl-N-phenylhydrazone) (42479-40-3) → {biacetyl di(methyl(phenyl)hydrazone)}bis(2,2'-bipyridine)ruthenium bis(hexafluorophosphate)

Guidance literature:

With NH₄PF₆; In ethanol; water; addn. of an aq. soln. of the Ru(II) complex to the hydrazone in ethanol; refluxing for 48 h; removal of solvent at 90°C under vac.; dissolving in H2O and washing with ether; dropwise addn. of the aq. soln. to NH4PF6 in H2O;; the ppt. was collected and dried under vac.; elem. anal.;;

upstream raw materials:

3-hydroxy-2-butanon

dimethylglyoxal