Benzoic acid, 4-(10-undecenyloxy)-, 4-carboxyphenyl ester

Base Information

• Chemical Name: Benzoic acid, 4-(10-undecenyloxy)-, 4-carboxyphenyl ester
• CAS No.: 900525-42-0
• Molecular Formula: C25H30O5
• Molecular Weight: 410.51
• Mol file: 900525-42-0.mol

Synonyms:

Chemical Property of Benzoic acid, 4-(10-undecenyloxy)-, 4-carboxyphenyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzoic acid, 4-(10-undecenyloxy)-, 4-carboxyphenyl ester

There total 7 articles about Benzoic acid, 4-(10-undecenyloxy)-, 4-carboxyphenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

10-undecen-1-yl p-toluenesulfonate (51148-67-5) → 4-((4-(undec-10-en-1-yloxy)benzoyl)oxy)benzoic acid (900525-42-0)

Guidance literature:

Multi-step reaction with 4 steps

1: potassium carbonate / acetone

2: potassium hydroxide / water; ethanol

3: dmap; dicyclohexyl-carbodiimide / dichloromethane / 48 h / 25 °C / Inert atmosphere

4: recorcinol; sodium chlorite; sodium dihydrogenphosphate dihydrate / water; tert-butyl alcohol / 48.5 h / 30 °C / Inert atmosphere

With dmap; sodium chlorite; sodium dihydrogenphosphate dihydrate; potassium carbonate; dicyclohexyl-carbodiimide; potassium hydroxide; recorcinol; In ethanol; dichloromethane; water; acetone; tert-butyl alcohol;

DOI:10.1002/pola.26373

Reference yield:

4-undec-10-enyloxybenzoic acid methyl ester (59100-35-5) → 4-((4-(undec-10-en-1-yloxy)benzoyl)oxy)benzoic acid (900525-42-0)

Guidance literature:

Multi-step reaction with 3 steps

1: potassium hydroxide / water; ethanol

2: dmap; dicyclohexyl-carbodiimide / dichloromethane / 48 h / 25 °C / Inert atmosphere

3: recorcinol; sodium chlorite; sodium dihydrogenphosphate dihydrate / water; tert-butyl alcohol / 48.5 h / 30 °C / Inert atmosphere

With dmap; sodium chlorite; sodium dihydrogenphosphate dihydrate; dicyclohexyl-carbodiimide; potassium hydroxide; recorcinol; In ethanol; dichloromethane; water; tert-butyl alcohol;

DOI:10.1002/pola.26373

Reference yield:

4-(10-undecenyloxy)benzoic acid (59100-95-7) + 4-hydroxy-benzaldehyde (123-08-0,65581-83-1) → 4-((4-(undec-10-en-1-yloxy)benzoyl)oxy)benzoic acid (900525-42-0)

Guidance literature:

Multi-step reaction with 2 steps

1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 48 h / 25 °C / Inert atmosphere

2: recorcinol; sodium chlorite; sodium dihydrogenphosphate dihydrate / water; tert-butyl alcohol / 48.5 h / 30 °C / Inert atmosphere

With dmap; sodium chlorite; sodium dihydrogenphosphate dihydrate; dicyclohexyl-carbodiimide; recorcinol; In dichloromethane; water; tert-butyl alcohol;

DOI:10.1002/pola.26373

upstream raw materials:

4-(10-undecenyloxy)benzoic acid

4-hydroxy-benzaldehyde

4-undec-10-enyloxybenzoic acid benzyl ester

Benzyl 4-hydroxybenzoate

Downstream raw materials:

C₆₀H₆₄O₁₀

3,4'-bis{4-[4-(10-undec-1-yloxy)benzoyloxy]benzoyloxy}biphenyl

C₆₅H₇₂F₂O₁₀

C₅₉H₆₂O₁₀