Benzene, [[(5-iodo-4-methyl-3-pentenyl)oxy]methyl]-, (Z)-

Base Information

Chemical Name:Benzene, [[(5-iodo-4-methyl-3-pentenyl)oxy]methyl]-, (Z)-
CAS No.:90107-92-9
Molecular Formula:C₁₃H₁₇IO
Molecular Weight:316.182
Hs Code.:

Synonyms:

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Chemical Property of Benzene, [[(5-iodo-4-methyl-3-pentenyl)oxy]methyl]-, (Z)-

Chemical Property:

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Technology Process of Benzene, [[(5-iodo-4-methyl-3-pentenyl)oxy]methyl]-, (Z)-

There total 1 articles about Benzene, [[(5-iodo-4-methyl-3-pentenyl)oxy]methyl]-, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 90107-92-9
((Z)-5-Iodo-4-methyl-pent-3-enyloxymethyl)-benzene

Guidance literature:: /BRN= 565586/, CH3I;

Reference yield:

: 90107-91-8,90107-92-9
C₁₃H₁₇IO

: 81491-34-1,81521-02-0,81521-05-3
Acetic acid (E)-6-((1R,4S)-4-{[2-(2-cyano-ethylsulfanyl)-phenyl]-methyl-carbamoyl}-2,2-dimethyl-cyclobutyl)-4-methyl-hex-3-enyl ester

Guidance literature:: Multi-step reaction with 8 steps

1: 730 mg / dimethylformamide / 18 h / Ambient temperature

2: 99.5 percent / n-butyllithium / tetrahydrofuran; hexamethylphosphoric acid triamide; hexane / 1.)-78 deg C, 2 h, 2.)1 h, ice-salt bath

3: 446 mg / tetra-n-butylammonium fluoride / tetrahydrofuran / 3 h / Ambient temperature

4: 84.2 percent / sodium amalgam, anh. sodium hydrogen phosphate / methanol / 1.)0 deg C, 2.)R_.T_.

5: 390 mg / Jones reagent / acetone / 0.5 h / 0 °C

6: Oxalyl chloride / benzene / 1.)30 min., r.t., 2.)2 h, 60-65 deg C

7: 550 mg / K₂CO₃ / tetrahydrofuran / 1.5 h / 0 °C

8: Dimethylsulfide, boron trifluoride etherate / CH₂Cl₂ / 0.67 h / 0 °C

With disodium hydrogenphosphate; sodium amalgam; n-butyllithium; jones reagent; oxalyl dichloride; dimethylsulfide; boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; potassium carbonate; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane; dichloromethane; N,N-dimethyl-formamide; acetone; benzene;
DOI:10.1021/jo00187a006

Reference yield:

: 90107-91-8,90107-92-9
C₁₃H₁₇IO

: 81491-36-3,81521-06-4,81521-07-5
N-Methyl-2'-<(2-cyanoethyl)thio>-2α-<(E)-6-<(methylsulfonyl)oxy>-3-methyl-3-hexenyl>-3,3-dimethylcyclobutane-1β-carboxanilide

Guidance literature:: Multi-step reaction with 10 steps

1: 730 mg / dimethylformamide / 18 h / Ambient temperature

2: 99.5 percent / n-butyllithium / tetrahydrofuran; hexamethylphosphoric acid triamide; hexane / 1.)-78 deg C, 2 h, 2.)1 h, ice-salt bath

3: 446 mg / tetra-n-butylammonium fluoride / tetrahydrofuran / 3 h / Ambient temperature

4: 84.2 percent / sodium amalgam, anh. sodium hydrogen phosphate / methanol / 1.)0 deg C, 2.)R_.T_.

5: 390 mg / Jones reagent / acetone / 0.5 h / 0 °C

6: Oxalyl chloride / benzene / 1.)30 min., r.t., 2.)2 h, 60-65 deg C

7: 550 mg / K₂CO₃ / tetrahydrofuran / 1.5 h / 0 °C

8: Dimethylsulfide, boron trifluoride etherate / CH₂Cl₂ / 0.67 h / 0 °C

9: K₂CO₃ / methanol / 1 h / 0 °C

10: Triethylamine / CH₂Cl₂ / 0.5 h / 0 °C

With disodium hydrogenphosphate; sodium amalgam; n-butyllithium; jones reagent; oxalyl dichloride; dimethylsulfide; boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; potassium carbonate; triethylamine; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane; dichloromethane; N,N-dimethyl-formamide; acetone; benzene;
DOI:10.1021/jo00187a006