1,3-Di(hydroxyimino)-5,5-dimethylcyclohexane

Base Information

• Chemical Name: 1,3-Di(hydroxyimino)-5,5-dimethylcyclohexane
• CAS No.: 37110-24-0
• Molecular Formula: C8H14N2O2
• Molecular Weight: 170.211
• Hs Code.: 2928000090
• NSC Number: 107388
• Mol file: 37110-24-0.mol

Synonyms:37110-24-0;5,5-Dimethylcyclohexane-1,3-dione dioxime;1,3-di(hydroxyimino)-5,5-dimethylcyclohexane;(NZ)-N-[(5Z)-5-hydroxyimino-3,3-dimethylcyclohexylidene]hydroxylamine;Dimedone Dioxime [for Determination of Co];NSC107388;AKOS024374465;NSC-107388;T70844;N-[(1E,5E)-5-(HYDROXYIMINO)-3,3-DIMETHYLCYCLOHEXYLIDENE]HYDROXYLAMINE

Chemical Property of 1,3-Di(hydroxyimino)-5,5-dimethylcyclohexane

Chemical Property:

• Vapor Pressure: 3.55E-05mmHg at 25°C
• Melting Point: 173oC
• Boiling Point: 329.2°Cat760mmHg
• Flash Point: 202.5°C
• PSA: 65.18000
• Density: 1.21g/cm³
• LogP: 1.85690
• XLogP3: 1.3
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 170.105527694
• Heavy Atom Count: 12
• Complexity: 209

Purity/Quality:

97% ^*data from raw suppliers

DimedoneDioxime ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1(CC(=NO)CC(=NO)C1)C
• Isomeric SMILES: CC1(C/C(=N/O)/C/C(=N\O)/C1)C

Technology Process of 1,3-Di(hydroxyimino)-5,5-dimethylcyclohexane

There total 2 articles about 1,3-Di(hydroxyimino)-5,5-dimethylcyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

dimedone (126-81-8) → 5,5-dimethyl-1,3-cyclohexanedionedioxime (37110-24-0)

Guidance literature:

With hydroxylamine hydrochloride; silica gel; at 50 ℃; for 4h; Temperature; Green chemistry;

Reference yield:

→ 5,5-dimethyl-1,3-cyclohexanedionedioxime (37110-24-0)

Guidance literature:

With hydroxylamine hydrochloride; sodium carbonate;

Reference yield: 74.0%

p-toluenesulfonyl chloride (98-59-9) + 5,5-dimethyl-1,3-cyclohexanedionedioxime (37110-24-0) → C15H19ClN2O3S

Guidance literature:

With N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; at 0 - 20 ℃; for 12h; Inert atmosphere;

DOI:10.1016/j.tetlet.2010.02.048

upstream raw materials:

dimedone

Downstream raw materials:

1,3-diamino-5,5-dimethylcyclohexane

5,5-Dimethyl-cyclohexane-1,2,3-trione dioxime

3-Chloro-5,5-dimethyl-3-nitroso-cyclohexanone oxime

6,6-dimethyl-6,7-dihydro-5H-2,3-dioxa-2aλ⁴-thia-1,4-diaza-cyclopenta[cd]indene