12-Methoxy-1,4,12-trioxododecan-2-yl benzoate

Base Information

Chemical Name:12-Methoxy-1,4,12-trioxododecan-2-yl benzoate
CAS No.:90511-09-4
Molecular Formula:C20H26O6
Molecular Weight:362.423
Hs Code.:
DSSTox Substance ID:DTXSID50523158

Synonyms:90511-09-4;12-Methoxy-1,4,12-trioxododecan-2-yl benzoate;DTXSID50523158

Suppliers and Price of 12-Methoxy-1,4,12-trioxododecan-2-yl benzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 12-Methoxy-1,4,12-trioxododecan-2-yl benzoate

Chemical Property:

XLogP3:3.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:15
Exact Mass:362.17293854
Heavy Atom Count:26
Complexity:453

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)CCCCCCCC(=O)CC(C=O)OC(=O)C1=CC=CC=C1

Technology Process of 12-Methoxy-1,4,12-trioxododecan-2-yl benzoate

There total 5 articles about 12-Methoxy-1,4,12-trioxododecan-2-yl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 90511-05-0
Benzoic acid 1-diethoxymethyl-10-methoxycarbonyl-3-oxo-decyl ester

: 90511-09-4
Benzoic acid 1-formyl-10-methoxycarbonyl-3-oxo-decyl ester

Guidance literature:: In tetrachloromethane; formic acid; at 25 ℃; for 0.583333h;
DOI:10.1016/S0040-4020(01)91249-9

Reference yield:

: 1931-63-1
methyl ester of azelaic acid aldehyde

: 90511-09-4
Benzoic acid 1-formyl-10-methoxycarbonyl-3-oxo-decyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 70 percent / hydroxylamine hydrochloride, sodium bicarbonate / H₂O / 24 h

2: 46 percent

3: H₂ / Ra-Ni / aq. ethanol / 4 h / Ambient temperature

4: 80 percent / pyridine / 50 h / 25 °C

5: 80 percent / CCl₄; formic acid / 0.58 h / 25 °C

With hydroxylamine hydrochloride; hydrogen; sodium hydrogencarbonate; Ra-Ni; In pyridine; tetrachloromethane; formic acid; ethanol; water;
DOI:10.1016/S0040-4020(01)91249-9

Reference yield:

: 90510-91-1
methyl 9-(hydroxyimino)nonanoate

: 90511-09-4
Benzoic acid 1-formyl-10-methoxycarbonyl-3-oxo-decyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 46 percent

2: H₂ / Ra-Ni / aq. ethanol / 4 h / Ambient temperature

3: 80 percent / pyridine / 50 h / 25 °C

4: 80 percent / CCl₄; formic acid / 0.58 h / 25 °C

With hydrogen; Ra-Ni; In pyridine; tetrachloromethane; formic acid; ethanol;
DOI:10.1016/S0040-4020(01)91249-9