1,2-Cyclohexanedione, 4-methyl-, dioxime

Base Information

• Chemical Name: 1,2-Cyclohexanedione, 4-methyl-, dioxime
• CAS No.: 18310-19-5
• Molecular Formula: C7H12 N2 O2
• Molecular Weight: 156.184
• Mol file: 18310-19-5.mol

Synonyms:1,2-Cyclohexanedione,4-methyl-, dioxime (6CI,7CI,8CI,9CI); 4-Methylcyclohexane-1,2-dione dioxime;4-Methylnioxime; NSC 88864

Chemical Property of 1,2-Cyclohexanedione, 4-methyl-, dioxime

Chemical Property:

• Vapor Pressure: 0.0029mmHg at 25°C
• Boiling Point: 253°Cat760mmHg
• Flash Point: 106.8°C
• PSA: 65.18000
• Density: 1.3g/cm³
• LogP: 1.46680

Purity/Quality:

1,2-CYCLOHEXANEDIONE, 4-METHYL-, DIOXIME 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2-Cyclohexanedione, 4-methyl-, dioxime

There total 7 articles about 1,2-Cyclohexanedione, 4-methyl-, dioxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-bromo-4-methylcyclohexanone (27579-55-1) → 4-methylcyclohexane-1,2-dione dioxime (18310-19-5)

Guidance literature:

With hydroxylamine;

DOI:10.1016/j.ejmech.2004.04.003

Reference yield:

1-methylcyclohexan-4-one (589-92-4) → 4-methylcyclohexane-1,2-dione dioxime (18310-19-5)

Guidance literature:

Multi-step reaction with 2 steps

1: bromine

2: hydroxylamine

With hydroxylamine; bromine;

DOI:10.1016/j.ejmech.2004.04.003

Reference yield:

Fe(4MNx)3(BOH)2 + boric acid (11113-50-1,14635-83-7) → 4-methylcyclohexane-1,2-dione dioxime (18310-19-5) + iron(II) (7439-89-6,15438-31-0)

Guidance literature:

With H(+); In water; in acidic soln.; byproducts: decomposition products of 4-methyl-nioxime (H24MNx); Kinetics;

DOI:10.1007/BF01299007

upstream raw materials:

2-bromo-4-methylcyclohexanone

1-methylcyclohexan-4-one

boric acid

Downstream raw materials:

4-methyl-cyclohexane-1,2-diyldiamine

4-methyl-trans-cyclohexane-1,2-diamine

4-methyl-trans-(+/-)-1,2-cyclohexanediamine

4-methyl-trans-(+/-)-1,2-cyclohexanediamine