(3aS)-3aβ,5,5a,6,7,9bα-Hexahydro-6β-hydroxy-5aα,9-dimethyl-3-methylenenaphtho[1,2-b]furan-2,8(3H,4H)-dione

Base Information

Chemical Name:(3aS)-3aβ,5,5a,6,7,9bα-Hexahydro-6β-hydroxy-5aα,9-dimethyl-3-methylenenaphtho[1,2-b]furan-2,8(3H,4H)-dione
CAS No.:27740-15-4
Molecular Formula:C₁₅H₁₈O₄
Molecular Weight:262.306
Hs Code.:
Mol file:27740-15-4.mol

Synonyms:Eudesma-4,11(13)-dien-12-oicacid, 1a,6a-dihydroxy-3-oxo-, g-lactone (8CI); Naphtho[1,2-b]furan-2,8(3H,4H)-dione,3a,5,5a,6,7,9b-hexahydro-6-hydroxy-5a,9-dimethyl-3-methylene-, [3aS-(3aa,5ab,6a,9bb)]-; Ludovicin C

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3aS)-3aβ,5,5a,6,7,9bα-Hexahydro-6β-hydroxy-5aα,9-dimethyl-3-methylenenaphtho[1,2-b]furan-2,8(3H,4H)-dione

Chemical Property:

Vapor Pressure:7.8E-12mmHg at 25°C
Boiling Point:494.1°Cat760mmHg
Flash Point:188.8°C
PSA：63.60000
Density:1.26g/cm³
LogP:1.53450

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (3aS)-3aβ,5,5a,6,7,9bα-Hexahydro-6β-hydroxy-5aα,9-dimethyl-3-methylenenaphtho[1,2-b]furan-2,8(3H,4H)-dione

There total 5 articles about (3aS)-3aβ,5,5a,6,7,9bα-Hexahydro-6β-hydroxy-5aα,9-dimethyl-3-methylenenaphtho[1,2-b]furan-2,8(3H,4H)-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 59444-49-4
C₁₅H₁₈O₅

: 27740-15-4,64929-15-3,87550-01-4
ludovicin C

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / sodium benzeneselenolate, AcOH / ethanol / 0.17 h / Ambient temperature

2: 1.) lithium diisopropylamide, diphenyldiselenide; 2.) H₂O₂, AcOH / 1.) THF, -40 deg C; 2.) THF

With diphenyl diselenide; dihydrogen peroxide; sodium phenylselenide; acetic acid; lithium diisopropyl amide; In ethanol;
DOI:10.1246/cl.1987.2387

Reference yield:

: 185432-27-3
(3S,3aS,5aS,9bS)-8-Hydroxy-3,5a,9-trimethyl-3a,4,5,5a,8,9b-hexahydro-3H-naphtho[1,2-b]furan-2-one

: 27740-15-4,64929-15-3,87550-01-4
ludovicin C

Guidance literature:: Multi-step reaction with 4 steps

1: MCPBA / 0 °C

2: 88 percent / Collins reagent

3: 80 percent / sodium benzeneselenolate, AcOH / ethanol / 0.17 h / Ambient temperature

4: 1.) lithium diisopropylamide, diphenyldiselenide; 2.) H₂O₂, AcOH / 1.) THF, -40 deg C; 2.) THF

With diphenyl diselenide; dihydrogen peroxide; sodium phenylselenide; acetic acid; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide; In ethanol;
DOI:10.1246/cl.1987.2387

Reference yield:

: 117152-29-1
C₁₅H₂₀O₅

: 27740-15-4,64929-15-3,87550-01-4
ludovicin C

Guidance literature:: Multi-step reaction with 3 steps

1: 88 percent / Collins reagent

2: 80 percent / sodium benzeneselenolate, AcOH / ethanol / 0.17 h / Ambient temperature

3: 1.) lithium diisopropylamide, diphenyldiselenide; 2.) H₂O₂, AcOH / 1.) THF, -40 deg C; 2.) THF

With diphenyl diselenide; dihydrogen peroxide; sodium phenylselenide; acetic acid; lithium diisopropyl amide; In ethanol;
DOI:10.1246/cl.1987.2387