5-(Cyclohex-1-en-1-yl)-2H-1,3-benzodioxole

Base Information

Chemical Name:5-(Cyclohex-1-en-1-yl)-2H-1,3-benzodioxole
CAS No.:90867-76-8
Molecular Formula:C13H14O2
Molecular Weight:202.253
Hs Code.:
DSSTox Substance ID:DTXSID40526219
Nikkaji Number:J2.644.896D
Wikidata:Q82394485

Synonyms:90867-76-8;5-(Cyclohex-1-en-1-yl)-2H-1,3-benzodioxole;SCHEMBL9618220;DTXSID40526219

Suppliers and Price of 5-(Cyclohex-1-en-1-yl)-2H-1,3-benzodioxole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 5-(Cyclohex-1-en-1-yl)-2H-1,3-benzodioxole

Chemical Property:

XLogP3:3.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:202.099379685
Heavy Atom Count:15
Complexity:259

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CCC(=CC1)C2=CC3=C(C=C2)OCO3

Technology Process of 5-(Cyclohex-1-en-1-yl)-2H-1,3-benzodioxole

There total 5 articles about 5-(Cyclohex-1-en-1-yl)-2H-1,3-benzodioxole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 1-(benzo[d][1,3]dioxol-5-yl)cyclohexanol

: 90867-76-8
5-(cyclohex-1-en-1-yl)benzo[d][1,3]dioxole

Guidance literature:: With acetic acid; at 118 ℃; for 1h;
DOI:10.1021/ja4100595

Reference yield:

: (1S,2R)-1-Benzo[1,3]dioxol-5-yl-2-bromo-cyclohexanecarbaldehyde

: 90867-76-8
5-(cyclohex-1-en-1-yl)benzo[d][1,3]dioxole

Guidance literature:: With sodium hydroxide; In 1,2-dimethoxyethane; at 20 ℃; for 12h;
DOI:10.1021/jo801434b

Reference yield:

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 90867-76-8
5-(cyclohex-1-en-1-yl)benzo[d][1,3]dioxole

Guidance literature:: Multi-step reaction with 2 steps

1.1: tert.-butyl lithium / diethyl ether / -78 °C / Inert atmosphere

1.2: 20 °C / Inert atmosphere

2.1: acetic acid / 1 h / 118 °C

With tert.-butyl lithium; acetic acid; In diethyl ether;
DOI:10.1021/ja4100595