1-Cyclohexene-1-carbothioic acid, 2-(2-propenyl)-, S-methyl ester

Base Information

Chemical Name:1-Cyclohexene-1-carbothioic acid, 2-(2-propenyl)-, S-methyl ester
CAS No.:90969-22-5
Molecular Formula:C11H16OS
Molecular Weight:196.313
Hs Code.:

Synonyms:

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Chemical Property of 1-Cyclohexene-1-carbothioic acid, 2-(2-propenyl)-, S-methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 1-Cyclohexene-1-carbothioic acid, 2-(2-propenyl)-, S-methyl ester

There total 3 articles about 1-Cyclohexene-1-carbothioic acid, 2-(2-propenyl)-, S-methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 90969-36-1
S-Methyl 2-<3-(Trimethylsilyl)-2-propenyl>cyclohexene-1-thioate

: 529-35-1
5,6,7,8-Tetrahydronaphthalen-1-ol

: 90969-22-5
S-Methyl-2-(2-propenyl)cyclohexene-1-thioate

Guidance literature:: With dimethyl(methylthio)sulfonium tetrafluoroborate; In acetonitrile; for 20h; Ambient temperature;
DOI:10.1021/jo00191a027

Reference yield:

: 17649-90-0
2-(bis-methylsulfanyl-methylene)-cyclohexanone

: 90969-22-5
S-Methyl-2-(2-propenyl)cyclohexene-1-thioate

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) sec-BuLi, Tetramethylethylenediamine / 1.) THF, a) 1 h, -78 deg C, b) 1 h, to 40 deg C, 2.) THF, a) 0,5 h, -78 eg C, b) 2 h, to 0 deg C

2: 78 percent / 10percent HBF₄ / tetrahydrofuran / Ambient temperature

3: 22 percent / Dimethyl(methylthio)sulfonium fluoroborate / acetonitrile / 20 h / Ambient temperature

With tetrafluoroboric acid; N,N,N,N,-tetramethylethylenediamine; dimethyl(methylthio)sulfonium tetrafluoroborate; sec.-butyllithium; In tetrahydrofuran; acetonitrile;
DOI:10.1021/jo00191a027

Reference yield:

: 90969-00-9
2--1-<3-(trimethylsilyl)-2-propenyl>cyclohexanol

: 90969-22-5
S-Methyl-2-(2-propenyl)cyclohexene-1-thioate

Guidance literature:: Multi-step reaction with 2 steps

1: 78 percent / 10percent HBF₄ / tetrahydrofuran / Ambient temperature

2: 22 percent / Dimethyl(methylthio)sulfonium fluoroborate / acetonitrile / 20 h / Ambient temperature

With tetrafluoroboric acid; dimethyl(methylthio)sulfonium tetrafluoroborate; In tetrahydrofuran; acetonitrile;
DOI:10.1021/jo00191a027