5-Undecenenitrile, 9-(2-hydroxyethyl)-6,10-dimethyl-2-(phenylthio)-

Base Information

Chemical Name:5-Undecenenitrile, 9-(2-hydroxyethyl)-6,10-dimethyl-2-(phenylthio)-
CAS No.:91201-47-7
Molecular Formula:C21H31NOS
Molecular Weight:345.549
Hs Code.:

Synonyms:

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Chemical Property of 5-Undecenenitrile, 9-(2-hydroxyethyl)-6,10-dimethyl-2-(phenylthio)-

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Technology Process of 5-Undecenenitrile, 9-(2-hydroxyethyl)-6,10-dimethyl-2-(phenylthio)-

There total 11 articles about 5-Undecenenitrile, 9-(2-hydroxyethyl)-6,10-dimethyl-2-(phenylthio)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 91201-42-2
(3R)-6,6-(Ethylenedioxy)-3-(1-methylethyl)-1-heptanol

: 91201-47-7
<2(R,S),5(E,Z),9R>-11-Hydroxy-6-methyl-9-(1-methylethyl)-2-(phenylthio)-5-undecenenitrile

Guidance literature:: Multi-step reaction with 6 steps

1: 52 g / pyridine / Ambient temperature

2: 35percent HClO₄ / tetrahydrofuran / 0.08 h / 0 °C

3: 1) Mg / 1) THF, 2) THF, -5 to 0 deg C

4: 47percent aqueous HBr / 0.17 h / < 0 deg C

5: 71 percent / 50percent NaOH / n-Bu₄NBr / benzene / 0.67 h / Heating

6: NaOMe / methanol / 0.5 h / Ambient temperature

With pyridine; sodium hydroxide; perchloric acid; hydrogen bromide; sodium methylate; magnesium; tetrabutylammomium bromide; In tetrahydrofuran; methanol; benzene;
DOI:10.1021/jo00192a007

Reference yield:

: 91201-41-1
Methyl (3R)-6,6-(ethylenedioxy)-3-(1-methylethyl)heptanoate

: 91201-47-7
<2(R,S),5(E,Z),9R>-11-Hydroxy-6-methyl-9-(1-methylethyl)-2-(phenylthio)-5-undecenenitrile

Guidance literature:: Multi-step reaction with 7 steps

1: 43.6 g / LiAlH₄ / diethyl ether / 1) -5 to 0 deg C 2) 0-10 deg C

2: 52 g / pyridine / Ambient temperature

3: 35percent HClO₄ / tetrahydrofuran / 0.08 h / 0 °C

4: 1) Mg / 1) THF, 2) THF, -5 to 0 deg C

5: 47percent aqueous HBr / 0.17 h / < 0 deg C

6: 71 percent / 50percent NaOH / n-Bu₄NBr / benzene / 0.67 h / Heating

7: NaOMe / methanol / 0.5 h / Ambient temperature

With pyridine; sodium hydroxide; lithium aluminium tetrahydride; perchloric acid; hydrogen bromide; sodium methylate; magnesium; tetrabutylammomium bromide; In tetrahydrofuran; methanol; diethyl ether; benzene;
DOI:10.1021/jo00192a007

Reference yield:

: 80845-81-4
(R)-(+)-3-isopropyl-6-oxoheptanoic acid

: 91201-47-7
<2(R,S),5(E,Z),9R>-11-Hydroxy-6-methyl-9-(1-methylethyl)-2-(phenylthio)-5-undecenenitrile

Guidance literature:: Multi-step reaction with 9 steps

1: diethyl ether / 0.08 h

2: 98 percent / p-TsOH / benzene / Heating

3: 43.6 g / LiAlH₄ / diethyl ether / 1) -5 to 0 deg C 2) 0-10 deg C

4: 52 g / pyridine / Ambient temperature

5: 35percent HClO₄ / tetrahydrofuran / 0.08 h / 0 °C

6: 1) Mg / 1) THF, 2) THF, -5 to 0 deg C

7: 47percent aqueous HBr / 0.17 h / < 0 deg C

8: 71 percent / 50percent NaOH / n-Bu₄NBr / benzene / 0.67 h / Heating

9: NaOMe / methanol / 0.5 h / Ambient temperature

With pyridine; sodium hydroxide; lithium aluminium tetrahydride; perchloric acid; hydrogen bromide; sodium methylate; magnesium; tetrabutylammomium bromide; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; diethyl ether; benzene;
DOI:10.1021/jo00192a007