Palladium, chloro(cyanomethyl)(triphenylphosphine)-

Base Information

• Chemical Name: Palladium, chloro(cyanomethyl)(triphenylphosphine)-
• CAS No.: 91482-74-5
• Molecular Formula: C20H17ClNPPd
• Molecular Weight: 444.208
• Mol file: 91482-74-5.mol

Synonyms:

Chemical Property of Palladium, chloro(cyanomethyl)(triphenylphosphine)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Palladium, chloro(cyanomethyl)(triphenylphosphine)-

There total 5 articles about Palladium, chloro(cyanomethyl)(triphenylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

trans-chloro(cyanomethyl)bis(triphenylphosphine)palladium(II) → Pd(2+)*CH2CN(1-)*Cl(1-)*P(C6H5)3=Pd(CH2CN)Cl(P(C6H5)3) (91482-74-5)

Guidance literature:

With dihydrogen peroxide; In dichloromethane; water; acetone; acetone and 30% aq. soln. of H2O2 added successively to CH2Cl2 soln. ofeduct, stirred for 40 h; concd., filtered; elem. anal.;

DOI:10.1246/bcsj.57.1012

Reference yield:

Pd(η5-C5H5)(CH2CN)(P(C6H5)3) → Pd(2+)*CH2CN(1-)*Cl(1-)*P(C6H5)3=Pd(CH2CN)Cl(P(C6H5)3) (91482-74-5)

Guidance literature:

With hydrogenchloride; In chloroform-d1; bubbling HCl through Pd complex suspension; pptn.;

DOI:10.1016/S0020-1693(00)82823-6

Reference yield:

Pd(η5-C5H5)(CH2CN)(P(C6H5)3) + trityl chloride (76-83-5) → Pd(2+)*CH2CN(1-)*Cl(1-)*P(C6H5)3=Pd(CH2CN)Cl(P(C6H5)3) (91482-74-5)

Guidance literature:

In diethyl ether; chloroform; addn. of triphenylmethyl chloride to Pd complex suspension under N2, room temp.; stirring, 2h; pptn.; filtration; washing (diethyl ether); elem. anal.;

DOI:10.1016/S0020-1693(00)82823-6

upstream raw materials:

bis(benzonitrile)palladium(II) dichloride

trityl chloride