tris(2-chlorophenyl)phosphane

Base Information

Chemical Name:tris(2-chlorophenyl)phosphane
CAS No.:6962-87-4
Molecular Formula:C₁₈H₁₂Cl₃P
Molecular Weight:365.626
Hs Code.:2903999090
Mol file:6962-87-4.mol

Synonyms:Phosphine,tris(o-chlorophenyl)- (8CI); NSC 54030; Tris(2-chlorophenyl)phosphine;Tris(o-chlorophenyl)phosphine

Suppliers and Price of tris(2-chlorophenyl)phosphane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 5 raw suppliers

Chemical Property of tris(2-chlorophenyl)phosphane

Chemical Property:

Vapor Pressure:1.12E-07mmHg at 25°C
Boiling Point:444.5°C at 760 mmHg
Flash Point:222.6°C
PSA：13.59000
LogP:5.40500

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of tris(2-chlorophenyl)phosphane

There total 2 articles about tris(2-chlorophenyl)phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 615-41-8
2-iodochlorobenzene

: 6962-87-4
tris(2-chlorophenyl)phosphorus

Guidance literature:: With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; phosphorus trichloride; In diethyl ether; -95 deg C, 1 h; -95 deg C to RT;
DOI:10.1016/0022-328X(85)87272-7

Reference yield:

: 6962-87-4
tris(2-chlorophenyl)phosphorus

Guidance literature:: With diethyl ether; hydrogen; phosphorus trichloride;
DOI:10.1039/jr9370000527

Reference yield:

: 494804-05-6
dodecacarbonyltetrarhodium⁽⁰⁾

: 6962-87-4
tris(2-chlorophenyl)phosphorus

: 4Rh*11CO*P(C₆H₄Cl)3=Rh₄(CO)11P(C₆H₄Cl)3

Guidance literature:: In not given; according to B.T. Heaton, L. Longhetti, D.M.P. Mingos, C.E. Briant, P.C.Mishall, B.R.C. Theobald, L. Garlaschelli and U. Sartorelli, J. Organom et. Chem., 13 (1981) 333.; detn. by (1)H NMR and GC/MS;
DOI:10.1016/1381-1169(94)00047-6