Perchloric acid;tris(2,6-dimethoxyphenyl)phosphane

Base Information

• Chemical Name: Perchloric acid;tris(2,6-dimethoxyphenyl)phosphane
• CAS No.: 91608-20-7
• Molecular Formula: C24H27O6P.ClHO4
• Molecular Weight: 542.907
• DSSTox Substance ID: DTXSID80517762
• Mol file: 91608-20-7.mol

Synonyms:91608-20-7;DTXSID80517762;Perchloric acid--tris(2,6-dimethoxyphenyl)phosphane (1/1)

Chemical Property of Perchloric acid;tris(2,6-dimethoxyphenyl)phosphane

Chemical Property:

• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 9
• Exact Mass: 542.1108618
• Heavy Atom Count: 36
• Complexity: 529

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=C(C(=CC=C1)OC)P(C2=C(C=CC=C2OC)OC)C3=C(C=CC=C3OC)OC.OCl(=O)(=O)=O

Technology Process of Perchloric acid;tris(2,6-dimethoxyphenyl)phosphane

There total 7 articles about Perchloric acid;tris(2,6-dimethoxyphenyl)phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tris(2,6-dimethoxyphenyl)phosphibe sulfide (123317-05-5) → tris(2,6-dimethoxyphenyl)phosphonium perchlorate (91608-20-7)

Guidance literature:

Multi-step reaction with 5 steps

1: 88 percent / benzene

2: 95 percent / (2,6)3P / methanol / Ambient temperature

3: 95 percent / 1M NaOH / methanol

4: 95 percent / 12M HCl / butan-2-one

5: 60percent aq. HClO₄

With hydrogenchloride; sodium hydroxide; perchloric acid; (2,6)3P; In methanol; butanone; benzene;

DOI:10.1246/bcsj.64.1782

Reference yield:

C28H36O6PS(1+)*I(1-) (129972-74-3) → tris(2,6-dimethoxyphenyl)phosphonium perchlorate (91608-20-7)

Guidance literature:

Multi-step reaction with 5 steps

1: 95 percent / (2,6)3P / methanol / Ambient temperature

2: 95 percent / 1M NaOH / methanol

3: 88 percent / S / toluene / 4 h / Ambient temperature

4: 55 percent / 6M HCl / butan-2-one / 4 h / 70 °C

5: 60percent aq. HClO₄

With hydrogenchloride; sodium hydroxide; perchloric acid; (2,6)3P; sulfur; In methanol; toluene; butanone;

DOI:10.1246/bcsj.64.1782

Reference yield:

C25H30O6PS(1+)*I(1-) (129972-72-1) → tris(2,6-dimethoxyphenyl)phosphonium perchlorate (91608-20-7)

Guidance literature:

Multi-step reaction with 5 steps

1: 95 percent / (2,6)3P / methanol / Ambient temperature

2: 95 percent / 1M NaOH / methanol

3: 88 percent / S / toluene / 4 h / Ambient temperature

4: 55 percent / 6M HCl / butan-2-one / 4 h / 70 °C

5: 60percent aq. HClO₄

With hydrogenchloride; sodium hydroxide; perchloric acid; (2,6)3P; sulfur; In methanol; toluene; butanone;

DOI:10.1246/bcsj.64.1782

upstream raw materials:

Tris-(2,6-dimethoxy-phenyl)-phosphane; hydrochloride

tris(2,6-dimethoxyphenyl)phosphibe sulfide

Tris-(2,6-dimethoxy-phenyl)-phosphane; hydriodide

C₂₅H₃₀O₆PS⁽¹⁺⁾*I^(1-)