2-[(4-Methoxyphenyl)sulfanyl]naphthalene-1,4-dione

Base Information

Chemical Name:2-[(4-Methoxyphenyl)sulfanyl]naphthalene-1,4-dione
CAS No.:89478-04-6
Molecular Formula:C17H12O3S
Molecular Weight:296.346
Hs Code.:
NSC Number:121719
DSSTox Substance ID:DTXSID20298225
Nikkaji Number:J3.419.150F
Wikidata:Q82039899

Synonyms:89478-04-6;2-[(4-methoxyphenyl)sulfanyl]naphthalene-1,4-dione;NSC121719;DTXSID20298225;NSC-121719

Suppliers and Price of 2-[(4-Methoxyphenyl)sulfanyl]naphthalene-1,4-dione

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of 2-[(4-Methoxyphenyl)sulfanyl]naphthalene-1,4-dione

Chemical Property:

Vapor Pressure:7.76E-09mmHg at 25°C
Boiling Point:465.3°C at 760 mmHg
Flash Point:235.4°C
Density:1.34g/cm³
XLogP3:3.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:3
Exact Mass:296.05071541
Heavy Atom Count:21
Complexity:449

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=CC=C(C=C1)SC2=CC(=O)C3=CC=CC=C3C2=O

Technology Process of 2-[(4-Methoxyphenyl)sulfanyl]naphthalene-1,4-dione

There total 3 articles about 2-[(4-Methoxyphenyl)sulfanyl]naphthalene-1,4-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.4%

: 80172-73-2
1-[(4-methoxyphenyl)sulfanyl]pyrrolidine-2,5-dione

: 130-15-4
[1,4]naphthoquinone

: 89478-04-6
2-[(4-methoxyl)phenylthio]-1,4-naphthoquinone

Guidance literature:: With ammonium cerium (IV) nitrate; C₁₀H₁₄CuO₄*C₂O₄^(2-)*Nb⁽²⁺⁾; N-fluorobis(benzenesulfon)imide; ytterbium(III) triflate; In acetonitrile; at 60 ℃; for 8h; Reagent/catalyst;

Reference yield:

: 1-(4-chlorophenyl)-2-(4-methoxyphenyl)disulfane

: 130-15-4
[1,4]naphthoquinone

: 89478-04-6
2-[(4-methoxyl)phenylthio]-1,4-naphthoquinone

: 89478-01-3
2-[(4-chloro)phenylthio]-1,4-naphthoquinone

Guidance literature:: With 1,3-bis-(diphenylphosphino)propane; H₃N*C₂H₆O₆S₂; tetrabutylammonium tetrafluoroborate; silver(I) acetate; In dimethyl sulfoxide; at 20 ℃; for 48h;
DOI:10.1021/acs.joc.5b00247

Reference yield:

: 5335-87-5
4,4'-dimethoxyphenyl disulfide

: 89478-04-6
2-[(4-methoxyl)phenylthio]-1,4-naphthoquinone

: 89478-01-3
2-[(4-chloro)phenylthio]-1,4-naphthoquinone

Guidance literature:: Multi-step reaction with 2 steps

1: silver(I) acetate; H₃N*C₂H₆O₆S₂; tetrabutylammonium tetrafluoroborate / dimethyl sulfoxide / 48 h / 20 °C

2: 1,3-bis-(diphenylphosphino)propane; silver(I) acetate; H₃N*C₂H₆O₆S₂; tetrabutylammonium tetrafluoroborate / dimethyl sulfoxide / 48 h / 20 °C

With 1,3-bis-(diphenylphosphino)propane; H₃N*C₂H₆O₆S₂; tetrabutylammonium tetrafluoroborate; silver(I) acetate; In dimethyl sulfoxide;
DOI:10.1021/acs.joc.5b00247