Technology Process of Cyclohexanone, 2-[[1-(trimethylsilyl)cyclopropyl]methylene]-
There total 4 articles about Cyclohexanone, 2-[[1-(trimethylsilyl)cyclopropyl]methylene]- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
3 A molecular sieve; 1,8-diazabicyclo[5.4.0]undec-7-ene;
In
dichloromethane;
for 18h;
Heating;
DOI:10.1021/jo00193a030
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 80 percent / MnO2 / CH2Cl2 / 48 h / Ambient temperature
2: 90 percent / pyridinium tosylate / methanol; benzene / 15 h / Ambient temperature
3: 90 percent / trimethylsilyl trifluoromethanesulfonate / CH2Cl2 / 8 h / -78 °C
4: 90 percent / 3 Angstroem molecular sieves, DBU / CH2Cl2 / 18 h / Heating
With
manganese(IV) oxide; trimethylsilyl trifluoromethanesulfonate; 3 A molecular sieve; pyridinium p-toluenesulfonate; 1,8-diazabicyclo[5.4.0]undec-7-ene;
In
methanol; dichloromethane; benzene;
DOI:10.1021/jo00193a030
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 1) diisobutylaluminium hydride, 2) 5percent sulfuric acid / 1) ether, -78 deg C, 2 h, 2) 1 h
2: 90 percent / pyridinium tosylate / methanol; benzene / 15 h / Ambient temperature
3: 90 percent / trimethylsilyl trifluoromethanesulfonate / CH2Cl2 / 8 h / -78 °C
4: 90 percent / 3 Angstroem molecular sieves, DBU / CH2Cl2 / 18 h / Heating
With
trimethylsilyl trifluoromethanesulfonate; 3 A molecular sieve; sulfuric acid; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene;
In
methanol; dichloromethane; benzene;
DOI:10.1021/jo00193a030
