sodium 2-(diphenylphosphine)benzoate

Base Information

• Chemical Name: sodium 2-(diphenylphosphine)benzoate
• CAS No.: 36882-17-4
• Molecular Formula: C19H15 O2 P . Na
• Molecular Weight: 328.282
• Hs Code.: 2916399090
• Mol file: 36882-17-4.mol

Synonyms:Benzoicacid, 2-(diphenylphosphino)-, sodium salt (9CI); 2-(Diphenylphosphino)benzoicacid sodium salt; Benzoic acid, o-(diphenylphosphino)-, sodium salt; Sodium2-(diphenylphosphino)benzoate

Chemical Property of sodium 2-(diphenylphosphine)benzoate

Chemical Property:

• Vapor Pressure: 6.4E-09mmHg at 25°C
• Boiling Point: 451°Cat760mmHg
• Flash Point: 226.5°C
• PSA: 53.72000
• Density: g/cm³
• LogP: 1.80830

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of sodium 2-(diphenylphosphine)benzoate

There total 2 articles about sodium 2-(diphenylphosphine)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

ortho-diphenylphosphinobenzoic acid (17261-28-8) → sodium 2-(diphenylphosphino)benzoate (36882-17-4)

Guidance literature:

With sodium hydroxide; In ethanol; at 20 ℃;

Reference yield:

sodium 2-chlorobenzoate (17264-74-3) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → sodium 2-(diphenylphosphino)benzoate (36882-17-4)

Guidance literature:

chloro-diphenylphosphine; With sodium; In tetrahydrofuran; at 25 - 66 ℃;

sodium 2-chlorobenzoate; In tetrahydrofuran; for 10h; Product distribution / selectivity;

Reference yield: 89.0%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + sodium 2-(diphenylphosphino)benzoate (36882-17-4) + benzyl chloride (100-44-7) → ([(C6H5)2PC6H4(μ-CO2)-κ3P,O,O']Ni(η1-CH2C6H5))2 (321679-15-6)

Guidance literature:

In tetrahydrofuran; addn. of Ni(COD)2 to mixt. of C6H5CH2Cl and (C6H5)2PC6H4COONa in THF;

DOI:10.1021/ja002042t

upstream raw materials:

sodium 2-chlorobenzoate

chloro-diphenylphosphine

ortho-diphenylphosphinobenzoic acid

Downstream raw materials:

([(C6H5)2PC6H4(μ-CO2)-κ3P,O,O']Ni(η1-CH2C6H5))2

ortho-diphenylphosphinobenzoic acid

Refernces

• 1、 -. "METHOD FOR SYNTHESIZING O-DIPHENYLPHOSPHINO BENZOIC ACID". Page/Page column 6. . Retrieved 2011/11/12.