1,4-Diphenyl-2,3-dioxabicyclo[2.2.2]oct-5-ene

Base Information

Chemical Name:1,4-Diphenyl-2,3-dioxabicyclo[2.2.2]oct-5-ene
CAS No.:91925-45-0
Molecular Formula:C18H16O2
Molecular Weight:264.324
Hs Code.:
DSSTox Substance ID:DTXSID00524115
Nikkaji Number:J908.610B

Synonyms:1,4-diphenyl-2,3-dioxabicyclo[2.2.2]oct-5-ene;91925-45-0;SCHEMBL9772633;DTXSID00524115

Suppliers and Price of 1,4-Diphenyl-2,3-dioxabicyclo[2.2.2]oct-5-ene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,4-Diphenyl-2,3-dioxabicyclo[2.2.2]oct-5-ene

Chemical Property:

XLogP3:3.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:264.115029749
Heavy Atom Count:20
Complexity:343

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC2(C=CC1(OO2)C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of 1,4-Diphenyl-2,3-dioxabicyclo[2.2.2]oct-5-ene

There total 3 articles about 1,4-Diphenyl-2,3-dioxabicyclo[2.2.2]oct-5-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 21113-62-2
1,4-diphenyl-1,3-cyclohexadiene

: 91925-45-0
1,4-diphenyl-2,3-dioxabicyclo[2.2.2]oct-5-ene

Guidance literature:: With rose bengal bis(triethylammonium) salt; oxygen; In dichloromethane; at 5 - 10 ℃; UV-irradiation;
DOI:10.1021/jo3001518

Reference yield: 74.0%

: 21113-62-2
1,4-diphenyl-1,3-cyclohexadiene

: 91925-45-0
1,4-diphenyl-2,3-dioxabicyclo<2.2.2>oct-5-ene

Guidance literature:: With oxygen; 5,15,10,20-tetraphenylporphyrin; In tetrachloromethane; at 15 ℃; for 1h; Irradiation;
DOI:10.1016/0022-328X(93)80433-C

Reference yield:

: 32651-20-0
1,4-diphenylcyclohexane-1,4-diol

: 91925-45-0
1,4-diphenyl-2,3-dioxabicyclo[2.2.2]oct-5-ene

Guidance literature:: Multi-step reaction with 2 steps

1: AcOH, conc. H₂SO₄

2: O₂ / CCl₄ / 0 °C / Irradiation; sensitizer: tetraphenylporphyn

With sulfuric acid; oxygen; acetic acid; In tetrachloromethane;
DOI:10.1002/hlca.19970800813