Benzaldehyde, 2-amino-3,4-dimethyl- (9CI)

Base Information

• Chemical Name: Benzaldehyde, 2-amino-3,4-dimethyl- (9CI)
• CAS No.: 92051-49-5
• Molecular Formula: C9H11NO
• Molecular Weight: 149.192
• Mol file: 92051-49-5.mol

Synonyms:I01-9911;BENZALDEHYDE,2-AMINO-3,4-DIMETHYL;

Chemical Property of Benzaldehyde, 2-amino-3,4-dimethyl- (9CI)

Chemical Property:

• PSA: 43.09000
• LogP: 2.27930

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzaldehyde, 2-amino-3,4-dimethyl- (9CI)

There total 1 articles about Benzaldehyde, 2-amino-3,4-dimethyl- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C9H13NO → dimethyl-3,4 amino-2 benzaldehyde (92051-49-5)

Guidance literature:

With manganese(IV) oxide; In dichloromethane; at 20 ℃; Inert atmosphere;

DOI:10.1021/acs.orglett.9b02714

Reference yield: 99.0%

2-(5-hydroxypent-1-enyl)phenol (180995-26-0) + dimethyl-3,4 amino-2 benzaldehyde (92051-49-5) → 2-((4aS,5R,10bR)-7,8-dimethyl-3,4,4a,5,6,10b-hexahydro-2H-pyrano[3,2-c]quinolin-5-yl)phenol

Guidance literature:

With C₃₅H₃₅O₄P; In dichloromethane; at 40 ℃; for 24h; stereoselective reaction; Inert atmosphere;

DOI:10.1021/acs.orglett.9b02714

Reference yield: 60.0%

dimethyl-3,4 amino-2 benzaldehyde (92051-49-5) + benzyl alcohol (100-51-6,185532-71-2) → 7,8-dimethyl-2-phenyl-1,4-dihydro-2H-benzo[d][1,3]oxazine

Guidance literature:

With 2,6-bis(-4-phenyl-4,5-dihydrooxazol-2-yl)pyridine; scandium tris(trifluoromethanesulfonate); In tetrachloromethane; at 50 ℃; for 36h; Schlenk technique; Molecular sieve; Inert atmosphere;

DOI:10.1021/acs.joc.1c01912

Downstream raw materials:

C₁₇H₁₇N₃