3-Cyclohexene-1-carboxylic acid, 5-(tributylstannyl)-, methyl ester, trans-

Base Information

• Chemical Name: 3-Cyclohexene-1-carboxylic acid, 5-(tributylstannyl)-, methyl ester, trans-
• CAS No.: 92097-38-6
• Molecular Formula: C20H38O2Sn
• Molecular Weight: 429.231
• Mol file: 92097-38-6.mol

Synonyms:

Chemical Property of 3-Cyclohexene-1-carboxylic acid, 5-(tributylstannyl)-, methyl ester, trans-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-Cyclohexene-1-carboxylic acid, 5-(tributylstannyl)-, methyl ester, trans-

There total 1 articles about 3-Cyclohexene-1-carboxylic acid, 5-(tributylstannyl)-, methyl ester, trans- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(tri-n-butyltin) (813-19-4) + cis-methyl 5-acetoxycyclohex-3-enecarboxylate (60729-55-7) → 5-methoxylcarbonyl-1-tributylstannylcyclohex-2-ene (92097-37-5) + CH3O2CC6H8Sn(C4H9)3 (92097-38-6)

Guidance literature:

With n-butyllithium; diethylaluminium chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; hexane; toluene; to THF soln. of hexabutylditin at 0°C (N2) added hexane soln. ofn-C4H9Li, stirred for 20 min, toluene soln. of diethylaluminium chloride added at -78°C, stirred for 1 h, THF soln. of Pd(P(C6H5)3)4 added, THF soln. of org. educt added,; warmed to room temp. for 1 h, stirred at 25°C for 20 h, excess of aq. NH3 added at 0°C; flash chromd. (SiO2, (C2H5)3N soln.);

DOI:10.1021/ja00334a059

upstream raw materials:

bis(tri-n-butyltin)

cis-methyl 5-acetoxycyclohex-3-enecarboxylate