Carbamic acid, N-[(1S)-3-diazo-1-methyl-2-oxopropyl]-N-methyl-,phenylmethyl ester

Base Information

Chemical Name:Carbamic acid, N-[(1S)-3-diazo-1-methyl-2-oxopropyl]-N-methyl-,phenylmethyl ester
CAS No.:922705-66-6
Molecular Formula:C13H15N3O3
Molecular Weight:261.28
Hs Code.:

Synonyms:Carbamic acid, N-[(1S)-3-diazo-1-methyl-2-oxopropyl]-N-methyl-,phenylmethyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Carbamic acid, N-[(1S)-3-diazo-1-methyl-2-oxopropyl]-N-methyl-,phenylmethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:: SDS file from LookChem

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Technology Process of Carbamic acid, N-[(1S)-3-diazo-1-methyl-2-oxopropyl]-N-methyl-,phenylmethyl ester

There total 2 articles about Carbamic acid, N-[(1S)-3-diazo-1-methyl-2-oxopropyl]-N-methyl-,phenylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 21691-41-8
(2S)-2-(methyl{[(phenylmethyl)oxy]carbonyl}amino)propanoic acid

: 922705-66-6
phenylmethyl [(1S)-3-diazo-1-methyl-2-oxopropyl]methylcarbamate

Guidance literature:: (2S)-2-(methyl{[(phenylmethyl)oxy]carbonyl}amino)propanoic acid; With 4-methyl-morpholine; chloroformic acid ethyl ester; In tetrahydrofuran; at -15 ℃; for 0.25h;

diazomethane; In tetrahydrofuran; dichloromethane; at -15 - 20 ℃;
DOI:10.1002/hlca.200690235

Reference yield:

: 37661-60-2
phenylmethyl (4S)-5-oxo-4-methyl-1,3-oxazolidine-3-carboxylate

: 922705-66-6
phenylmethyl [(1S)-3-diazo-1-methyl-2-oxopropyl]methylcarbamate

Guidance literature:: Multi-step reaction with 2 steps

1.1: 89 percent / Et₃SiH; CF₃COOH / CH₂Cl₂

2.1: ClCOOEt; N-methylmorpholine / tetrahydrofuran / 0.25 h / -15 °C

2.2: 70 percent / tetrahydrofuran; CH₂Cl₂ / -15 - 20 °C

With 4-methyl-morpholine; triethylsilane; chloroformic acid ethyl ester; trifluoroacetic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1002/hlca.200690235