1-Bromo-4-methoxy-2,5-bis(methoxymethoxy)benzene

Base Information

Chemical Name:1-Bromo-4-methoxy-2,5-bis(methoxymethoxy)benzene
CAS No.:923025-92-7
Molecular Formula:C11H15BrO5
Molecular Weight:307.141
Hs Code.:
DSSTox Substance ID:DTXSID70582707
Wikidata:Q82474209

Synonyms:1-Bromo-4-methoxy-2,5-bis(methoxymethoxy)benzene;923025-92-7;DTXSID70582707

Suppliers and Price of 1-Bromo-4-methoxy-2,5-bis(methoxymethoxy)benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-Bromo-4-methoxy-2,5-bis(methoxymethoxy)benzene

Chemical Property:

XLogP3:2.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:7
Exact Mass:306.01029
Heavy Atom Count:17
Complexity:204

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COCOC1=CC(=C(C=C1OC)OCOC)Br

Technology Process of 1-Bromo-4-methoxy-2,5-bis(methoxymethoxy)benzene

There total 3 articles about 1-Bromo-4-methoxy-2,5-bis(methoxymethoxy)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 131223-60-4
2-methoxy-1,4-bis-methoxymethoxy-benzene

: 923025-92-7
1-bromo-4-methoxy-2,5-bis(methoxymethoxy)benzene

Guidance literature:: With pyridinium hydrobromide perbromide; sodium hydrogencarbonate; In methanol; at 20 ℃; for 0.416667h;
DOI:10.1021/jm061123i

Reference yield: 82.0%

: 107-30-2
chloromethyl methyl ether

: 174769-28-9
2-bromo-5-methoxy-1,4-dihydroxybenzene

: 923025-92-7
1-bromo-4-methoxy-2,5-bis(methoxymethoxy)benzene

Guidance literature:: With sodium hydride; In tetrahydrofuran; mineral oil; at 0 - 20 ℃; for 24h;
DOI:10.1021/acs.joc.9b02785

Reference yield:

: 824-46-4
methoxyhydroquinone

: 923025-92-7
1-bromo-4-methoxy-2,5-bis(methoxymethoxy)benzene

Guidance literature:: Multi-step reaction with 2 steps

1.1: NaH / tetrahydrofuran / 0.17 h / 0 °C

1.2: 75 percent / tetrahydrofuran / 24 h

2.1: 89 percent / NaHCO₃; pyridium hydrobromide perbromide / methanol / 0.42 h / 20 °C

With pyridinium hydrobromide perbromide; sodium hydride; sodium hydrogencarbonate; In tetrahydrofuran; methanol;
DOI:10.1021/jm061123i