12-Tridecenoic acid, 3,7-dihydroxy-4,4,6,8,12-pentamethyl-5-oxo-, (1S,5S)-5-ethenyl-2-methyl-3-phenyl-2-cyclopenten-1-yl ester, (3S,6R,7S,8S)-

Base Information

Chemical Name:12-Tridecenoic acid, 3,7-dihydroxy-4,4,6,8,12-pentamethyl-5-oxo-, (1S,5S)-5-ethenyl-2-methyl-3-phenyl-2-cyclopenten-1-yl ester, (3S,6R,7S,8S)-
CAS No.:923956-13-2
Molecular Formula:C32H46O5
Molecular Weight:510.714
Hs Code.:

12-Tridecenoic acid, 3,7-dihydroxy-4,4,6,8,12-pentamethyl-5-oxo-,
(1S,5S)-5-ethenyl-2-methyl-3-phenyl-2-cyclopenten-1-yl ester,
(3S,6R,7S,8S)-

Synonyms:

Suppliers and Price of 12-Tridecenoic acid, 3,7-dihydroxy-4,4,6,8,12-pentamethyl-5-oxo-, (1S,5S)-5-ethenyl-2-methyl-3-phenyl-2-cyclopenten-1-yl ester, (3S,6R,7S,8S)-

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 12-Tridecenoic acid, 3,7-dihydroxy-4,4,6,8,12-pentamethyl-5-oxo-, (1S,5S)-5-ethenyl-2-methyl-3-phenyl-2-cyclopenten-1-yl ester, (3S,6R,7S,8S)-

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Technology Process of 12-Tridecenoic acid, 3,7-dihydroxy-4,4,6,8,12-pentamethyl-5-oxo-, (1S,5S)-5-ethenyl-2-methyl-3-phenyl-2-cyclopenten-1-yl ester, (3S,6R,7S,8S)-

There total 18 articles about 12-Tridecenoic acid, 3,7-dihydroxy-4,4,6,8,12-pentamethyl-5-oxo-, (1S,5S)-5-ethenyl-2-methyl-3-phenyl-2-cyclopenten-1-yl ester, (3S,6R,7S,8S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1032297-98-5
C₃₈H₆₀O₅Si

: 923956-13-2
(3S,6R,7S,8S)-3,7-dihydroxy-4,4,6,8,12-pentamethyl-5-oxotridec-12-enoic acid (1S,2E,5S)-2-methyl-3-phenyl-5-vinylcyclopent-2-enyl ester

Guidance literature:: C₃₈H₆₀O₅Si; With tris(dimethylamino)sulfonium trimethylsilyldifluoride; In ethanol; ethyl acetate; N,N-dimethyl-formamide; for 24h;

With water; In ethanol; ethyl acetate; N,N-dimethyl-formamide; pH=7;

Reference yield:

: 923956-20-1
(1S,2E,5S)-triethyl-(2-methyl-3-phenyl-5-vinylcyclopent-2-enyloxy)silane

: 923956-13-2
(3S,6R,7S,8S)-3,7-dihydroxy-4,4,6,8,12-pentamethyl-5-oxotridec-12-enoic acid (1S,2E,5S)-2-methyl-3-phenyl-5-vinylcyclopent-2-enyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.5 h / 0 °C

2: dmap; dicyclohexyl-carbodiimide / dichloromethane / 16.25 h / 0 - 20 °C

3: ammonium chloride; zinc / ethanol / 0.75 h / 20 °C

4: tris(dimethylamino)sulfonium trimethylsilyldifluoride / N,N-dimethyl-formamide / 48 h

With dmap; tetrabutyl ammonium fluoride; tris(dimethylamino)sulfonium trimethylsilyldifluoride; ammonium chloride; dicyclohexyl-carbodiimide; zinc; In tetrahydrofuran; ethanol; dichloromethane; N,N-dimethyl-formamide;

Reference yield:

: 923956-09-6
(1R,2S,3E)-3-methyl-4-phenyl-2-triethylsilanyloxycyclopent-3-enecarboxylic acid ethyl ester

: 923956-13-2
(3S,6R,7S,8S)-3,7-dihydroxy-4,4,6,8,12-pentamethyl-5-oxotridec-12-enoic acid (1S,2E,5S)-2-methyl-3-phenyl-5-vinylcyclopent-2-enyl ester

Guidance literature:: Multi-step reaction with 6 steps

1.1: diisobutylaluminium hydride / hexane; toluene / 1 h / -78 °C

2.1: n-butyllithium / tetrahydrofuran; hexanes / 0.5 h / 0 °C

2.2: 0.5 h / 0 °C

3.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.5 h / 0 °C

4.1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 16.25 h / 0 - 20 °C

5.1: ammonium chloride; zinc / ethanol / 0.75 h / 20 °C

6.1: tris(dimethylamino)sulfonium trimethylsilyldifluoride / N,N-dimethyl-formamide / 48 h

With dmap; n-butyllithium; tetrabutyl ammonium fluoride; tris(dimethylamino)sulfonium trimethylsilyldifluoride; diisobutylaluminium hydride; ammonium chloride; dicyclohexyl-carbodiimide; zinc; In tetrahydrofuran; hexanes; ethanol; hexane; dichloromethane; N,N-dimethyl-formamide; toluene;