Benzene, 1,3,5-trichloro-2-[[[(4R,5S)-5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-[(4- methoxyphenyl)methoxy]-5-methyl-6-hepten-1-yl]oxy]methyl]-

Base Information

Chemical Name:Benzene, 1,3,5-trichloro-2-[[[(4R,5S)-5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-[(4- methoxyphenyl)methoxy]-5-methyl-6-hepten-1-yl]oxy]methyl]-
CAS No.:924282-45-1
Molecular Formula:C29H41Cl3O4Si
Molecular Weight:588.087
Hs Code.:

Benzene,
1,3,5-trichloro-2-[[[(4R,5S)-5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-[(4-
methoxyphenyl)methoxy]-5-methyl-6-hepten-1-yl]oxy]methyl]-

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzene, 1,3,5-trichloro-2-[[[(4R,5S)-5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-[(4- methoxyphenyl)methoxy]-5-methyl-6-hepten-1-yl]oxy]methyl]-

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Technology Process of Benzene, 1,3,5-trichloro-2-[[[(4R,5S)-5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-[(4- methoxyphenyl)methoxy]-5-methyl-6-hepten-1-yl]oxy]methyl]-

There total 1 articles about Benzene, 1,3,5-trichloro-2-[[[(4R,5S)-5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-[(4- methoxyphenyl)methoxy]-5-methyl-6-hepten-1-yl]oxy]methyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 924282-38-2
4-(4-methoxy-benzyloxy)-3-methyl-7-(2,4,6-trichloro-benzyloxy)-hept-1-en-3-ol

: 69739-34-0
t-butyldimethylsiyl triflate

: 924282-45-1
tert-butyl-{1-[1-(4-methoxy-benzyloxy)-4-(2,4,6-trichloro-benzyloxy)-butyl]-1-methyl-allyloxy}-dimethyl-silane

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 0 - 20 ℃;
DOI:10.1016/j.tetlet.2006.11.058

Reference yield: 73.0%

: 924282-45-1
tert-butyl-{1-[1-(4-methoxy-benzyloxy)-4-(2,4,6-trichloro-benzyloxy)-butyl]-1-methyl-allyloxy}-dimethyl-silane

: 924282-30-4
3-(tert-butyl-dimethyl-silanyloxy)-3-methyl-7-(2,4,6-trichloro-benzyloxy)-hept-1-en-4-ol

Guidance literature:: With sodium hydrogencarbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; at 20 ℃; for 2h;
DOI:10.3987/com-07-s(w)39

Reference yield:

: 924282-45-1
tert-butyl-{1-[1-(4-methoxy-benzyloxy)-4-(2,4,6-trichloro-benzyloxy)-butyl]-1-methyl-allyloxy}-dimethyl-silane

: 924282-44-0
C₅₅H₉₇Cl₃O₈Si₃

Guidance literature:: Multi-step reaction with 5 steps

1.1: 70 percent / DDQ; aq. NaHCO₃ / CH₂Cl₂ / 35 °C

2.1: 2,4,5-trichlorobenzoyl chloride; Et₃N / tetrahydrofuran / 20 °C

2.2: 81 percent / DMAP / tetrahydrofuran; toluene / 20 °C

3.1: 94 percent / CSA / methanol / 0 °C

4.1: 76 percent / second generation Grubbs' catalyst / benzene / 80 °C

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; camphor-10-sulfonic acid; sodium hydrogencarbonate; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; 2,4,6-trichlorobenzoyl chloride; In tetrahydrofuran; methanol; dichloromethane; benzene; 2.1: Yamaguchi reaction;
DOI:10.1016/j.tetlet.2006.11.058