Methanesulfonic acid, 1,1,1-trifluoro-, 4-[1-formyl-2-(methoxymethoxy)ethyl]-3-[(methoxymethoxy)methyl]-1-[(4- methylphenyl)sulfonyl]-7-(phenylmethoxy)-1H-indol-5-yl ester

Base Information

Chemical Name:Methanesulfonic acid, 1,1,1-trifluoro-, 4-[1-formyl-2-(methoxymethoxy)ethyl]-3-[(methoxymethoxy)methyl]-1-[(4- methylphenyl)sulfonyl]-7-(phenylmethoxy)-1H-indol-5-yl ester
CAS No.:925463-53-2
Molecular Formula:C31H32F3NO11S2
Molecular Weight:715.722
Hs Code.:

Methanesulfonic acid, 1,1,1-trifluoro-,
4-[1-formyl-2-(methoxymethoxy)ethyl]-3-[(methoxymethoxy)methyl]-1-[(4-
methylphenyl)sulfonyl]-7-(phenylmethoxy)-1H-indol-5-yl ester

Synonyms:

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Chemical Property of Methanesulfonic acid, 1,1,1-trifluoro-, 4-[1-formyl-2-(methoxymethoxy)ethyl]-3-[(methoxymethoxy)methyl]-1-[(4- methylphenyl)sulfonyl]-7-(phenylmethoxy)-1H-indol-5-yl ester

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Technology Process of Methanesulfonic acid, 1,1,1-trifluoro-, 4-[1-formyl-2-(methoxymethoxy)ethyl]-3-[(methoxymethoxy)methyl]-1-[(4- methylphenyl)sulfonyl]-7-(phenylmethoxy)-1H-indol-5-yl ester

There total 14 articles about Methanesulfonic acid, 1,1,1-trifluoro-, 4-[1-formyl-2-(methoxymethoxy)ethyl]-3-[(methoxymethoxy)methyl]-1-[(4- methylphenyl)sulfonyl]-7-(phenylmethoxy)-1H-indol-5-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: trifluoro-methanesulfonic acid 5-benzyloxy-2,3-bis-(1-formyl-2-methoxymethoxy-ethyl)-4-(toluene-4-sulfonylamino)-phenyl ester

: 925463-53-2
trifluoro-methanesulfonic acid 7-benzyloxy-4-(1-formyl-2-methoxymethoxy-ethyl)-3-methoxymethoxymethyl-1-(toluene-4-sulfonyl)-1H-indol-5-yl ester

Guidance literature:: With methanesulfonyl chloride; triethylamine; In tetrahydrofuran; for 0.333333h;
DOI:10.1021/jo062064j

Reference yield:

: (2E,4E)-1,6-Bis-methoxymethoxy-hexa-2,4-diene

: 925463-53-2
trifluoro-methanesulfonic acid 7-benzyloxy-4-(1-formyl-2-methoxymethoxy-ethyl)-3-methoxymethoxymethyl-1-(toluene-4-sulfonyl)-1H-indol-5-yl ester

Guidance literature:: Multi-step reaction with 6 steps

1: CH₂Cl₂ / 24 h / 9308660 Torr

2: 0.860 g / 1,8-diazabicyclo[5.4.0]undec-7-ene / CH₂Cl₂ / 0.5 h

3: 98 percent / sodium hydride / tetrahydrofuran / 0.67 h / 0 - 20 °C

4: osmium tetroxide; 2,6-lutidine; N-methylmorpholine N-oxide / tetrahydrofuran; H₂O

5: sodium periodate on silica gel / CH₂Cl₂ / 2.5 h

6: 0.790 g / triethylamine; methanesulfonyl chloride / tetrahydrofuran / 0.33 h

With 2,6-dimethylpyridine; sodium periodate; osmium(VIII) oxide; sodium hydride; methanesulfonyl chloride; 4-methylmorpholine N-oxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; In tetrahydrofuran; dichloromethane; water; 1: Diels-Alder reaction;
DOI:10.1021/jo062064j

Reference yield:

: 925463-43-0
4-amino-3-benzyloxy-phenol

: 925463-53-2
trifluoro-methanesulfonic acid 7-benzyloxy-4-(1-formyl-2-methoxymethoxy-ethyl)-3-methoxymethoxymethyl-1-(toluene-4-sulfonyl)-1H-indol-5-yl ester

Guidance literature:: Multi-step reaction with 8 steps

1: 84 percent / pyridine / CH₂Cl₂ / 4 h / 20 °C

2: 96 percent / sodium periodate on silica gel / CH₂Cl₂ / 4 h

3: CH₂Cl₂ / 24 h / 9308660 Torr

4: 0.860 g / 1,8-diazabicyclo[5.4.0]undec-7-ene / CH₂Cl₂ / 0.5 h

5: 98 percent / sodium hydride / tetrahydrofuran / 0.67 h / 0 - 20 °C

6: osmium tetroxide; 2,6-lutidine; N-methylmorpholine N-oxide / tetrahydrofuran; H₂O

7: sodium periodate on silica gel / CH₂Cl₂ / 2.5 h

8: 0.790 g / triethylamine; methanesulfonyl chloride / tetrahydrofuran / 0.33 h

With pyridine; 2,6-dimethylpyridine; sodium periodate; osmium(VIII) oxide; sodium hydride; methanesulfonyl chloride; 4-methylmorpholine N-oxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; In tetrahydrofuran; dichloromethane; water; 3: Diels-Alder reaction;
DOI:10.1021/jo062064j