Cyclohexene, 3-(chlorodiethoxysilyl)-

Base Information

• Chemical Name: Cyclohexene, 3-(chlorodiethoxysilyl)-
• CAS No.: 925916-26-3
• Molecular Formula: C10H19ClO2Si
• Molecular Weight: 234.798
• Mol file: 925916-26-3.mol

Synonyms:

Chemical Property of Cyclohexene, 3-(chlorodiethoxysilyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cyclohexene, 3-(chlorodiethoxysilyl)-

There total 1 articles about Cyclohexene, 3-(chlorodiethoxysilyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

tetraethoxy orthosilicate (78-10-4) + (+/-)-3-trichlorosilylcyclohexene (18139-74-7) → C10H19ClO2Si (925916-26-3)

Guidance literature:

With triphenylphosphine; at 20 ℃; for 168h;

DOI:10.1016/j.jorganchem.2006.08.045

Reference yield: 40.0%

C10H19ClO2Si (925916-26-3) + (E)-1-(2-iodophenyl)-2-phenyldiazene (51343-11-4) → C22H28N2O2Si (925916-30-9)

Guidance literature:

(E)-1-(2-iodophenyl)-2-phenyldiazene; With n-butyllithium; In tetrahydrofuran; hexane; at -105 ℃;

C₁₀H₁₉ClO₂Si; In tetrahydrofuran; hexane; at -105 - 0 ℃; for 22h; Further stages.;

DOI:10.1016/j.jorganchem.2006.08.045

Reference yield:

C10H19ClO2Si (925916-26-3) → C18H18F2N2Si

Guidance literature:

Multi-step reaction with 2 steps

1.1: n-BuLi / hexane; tetrahydrofuran / -105 °C

1.2: 40 percent / hexane; tetrahydrofuran / 22 h / -105 - 0 °C

2.1: 31 percent / BF₃*Et₂O / diethyl ether / 20 h / 20 °C

With n-butyllithium; boron trifluoride diethyl etherate; In tetrahydrofuran; diethyl ether; hexane;

DOI:10.1016/j.jorganchem.2006.08.045

upstream raw materials:

tetraethoxy orthosilicate

(+/-)-3-trichlorosilylcyclohexene

Downstream raw materials:

C₂₂H₂₈N₂O₂Si