2,5-Cyclohexadiene-1,4-dione, 2-methoxy-6-(10-pentadecenyl)-, (Z)-

Base Information

Chemical Name:2,5-Cyclohexadiene-1,4-dione, 2-methoxy-6-(10-pentadecenyl)-, (Z)-
CAS No.:97987-89-8
Molecular Formula:C22H34O3
Molecular Weight:346.51
Hs Code.:
Mol file:97987-89-8.mol

Synonyms:2-methoxy-6-((Z)-10'-pentadecenyl)-1,4-benzoquinone;ardisianone A

Suppliers and Price of 2,5-Cyclohexadiene-1,4-dione, 2-methoxy-6-(10-pentadecenyl)-, (Z)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 32 raw suppliers

Chemical Property of 2,5-Cyclohexadiene-1,4-dione, 2-methoxy-6-(10-pentadecenyl)-, (Z)-

Chemical Property:

Vapor Pressure:3.39E-08mmHg at 25°C
Boiling Point:447.3°Cat760mmHg
Flash Point:190.7°C
PSA：43.37000
Density:0.986g/cm³
LogP:5.35890
XLogP3:5.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:13
Exact Mass:346.25079494
Heavy Atom Count:25
Complexity:499

Purity/Quality:: ≥94% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCCC(CCC=CCCCC(C)OC)C1=CC(=O)C=CC1=O
Isomeric SMILES:CCCCCC(CC/C=C/CCCC(C)OC)C1=CC(=O)C=CC1=O

Technology Process of 2,5-Cyclohexadiene-1,4-dione, 2-methoxy-6-(10-pentadecenyl)-, (Z)-

There total 10 articles about 2,5-Cyclohexadiene-1,4-dione, 2-methoxy-6-(10-pentadecenyl)-, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 2-Methoxy-6-<(Z)-10-pentadecenyl>phenol

: 97987-89-8
belamcandaquinone

Guidance literature:: With salcomine; oxygen; In N,N-dimethyl-formamide; for 16h; under 750.06 Torr; Ambient temperature;

Reference yield: 62.7%

: 137786-94-8
belamcandol B

: 97987-89-8
belamcandaquinone

Guidance literature:: With salcomine; oxygen; In N,N-dimethyl-formamide; for 14h;
DOI:10.1248/cpb.41.561

Reference yield:

: 67136-13-4
1-(tetrahydro-2-pyranyloxy)-9-decene

: 97987-89-8
belamcandaquinone

Guidance literature:: Multi-step reaction with 8 steps

1: 1.) O₃, 2.) Et₃N / 1.) CH₂Cl₂, -78 deg C, 2.) CH₂Cl₂, from -78 deg C to RT

2: 1.) n-BuLi / 1.) THF, hexane, RT, 15 min, 2.) THF, hexane, RT, 18 h

3: 91 percent / H₂ / 10percent Pd/C / ethanol / 12 h

4: 94 percent / p-toluenesulfonic acid, H₂O / tetrahydrofuran / 18 h / Ambient temperature

5: 1.) (COCl)2, DMSO, 2.) Et₃N / 1.) CH₂Cl₂, -78 deg C, 1 h, 2.) CH₂Cl₂, 0 deg C, 20 min

6: 1.) t-BuOK / 1.) THF, RT, 30 min, 2.) THF, 1 h

7: 91 percent / ethanethiol, NaH / dimethylformamide / 3 h / Heating

8: 62.7 percent / salcomine, O₂ / dimethylformamide / 14 h

With n-butyllithium; oxalyl dichloride; salcomine; potassium tert-butylate; water; hydrogen; oxygen; sodium hydride; toluene-4-sulfonic acid; ozone; dimethyl sulfoxide; triethylamine; ethanethiol; palladium on activated charcoal; In tetrahydrofuran; ethanol; N,N-dimethyl-formamide;
DOI:10.1248/cpb.41.561