4-ethenyl-2,6-dimethoxyphenol

Base Information

• Chemical Name: 4-ethenyl-2,6-dimethoxyphenol
• CAS No.: 31872-14-7
• Molecular Formula: C₁₀H₁₂O₃
• Molecular Weight: 180.203
• Mol file: 31872-14-7.mol

Synonyms:Phenol,2,6-dimethoxy-4-vinyl-, polymers (8CI); Poly(3,5-dimethoxy-4-hydroxystyrene);Poly(4-hydroxy-3,5-dimethoxystyrene)

Chemical Property of 4-ethenyl-2,6-dimethoxyphenol

Chemical Property:

• Vapor Pressure: 0.00163mmHg at 25°C
• Boiling Point: 285.4°Cat760mmHg
• Flash Point: 126.4°C
• Density: 1.113g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-ethenyl-2,6-dimethoxyphenol

There total 17 articles about 4-ethenyl-2,6-dimethoxyphenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

ethyltriphenylphosphonium bromide (1530-32-1) + syringic aldehyde (134-96-3) → canolol (28343-22-8,31872-14-7)

Guidance literature:

ethyl(trisphenyl)phosphonium bromide; With potassium-t-butoxide; In tetrahydrofuran; at 20 ℃; for 0.5h; Inert atmosphere; Sealed tube;

syringic aldehyde; In tetrahydrofuran; at 0 - 20 ℃; for 40h; Inert atmosphere; Sealed tube;

DOI:10.1021/acs.orglett.2c00566

Reference yield: 94.0%

sinapinic acid (530-59-6,7362-37-0) → canolol (28343-22-8,31872-14-7)

Guidance literature:

With Cocos nucifera juice; at 20 ℃; for 48h; Inert atmosphere;

DOI:10.1016/j.molcatb.2012.06.004

Reference yield: 90.0%

1-(4-Hydroxy-3,5-dimethoxyphenyl)ethanol (33900-62-8) → canolol (28343-22-8,31872-14-7)

Guidance literature:

With MoO₂Cl₂(DMSO)2; dimethyl sulfoxide; for 0.166667h; Microwave irradiation;

DOI:10.1002/cssc.201800598

upstream raw materials:

malonic acid

syringic aldehyde

sinapinic acid

C₄H₁₁N*C₁₁H₁₂O₅

Refernces

• 1、 Cardona-G, Wilson,Hernández, Cristian,Herrera-R, Angie,Moreno, Gustavo. "New hybrids based on curcumin and resveratrol: Synthesis, cytotoxicity and antiproliferative activity against colorectal cancer cells". . . Retrieved 2021/05/26.
• 2、 Hu, Zhenhua,Li, Suxiang,Lu, Fachuang,Shi, Lanlan,Wang, Chen,Yue, Fengxia,Zhang, Han,Zhao, Chengke. "Profiling of the formation of lignin-derived monomers and dimers from: Eucalyptus alkali lignin". supporting information. p. 7366 - 7375. Retrieved 2020/11/18.