(2-Methyl-3-phenylprop-2-enyl)hydrazine

Base Information

• Chemical Name: (2-Methyl-3-phenylprop-2-enyl)hydrazine
• CAS No.: 92882-31-0
• Molecular Formula: C10H14N2
• Molecular Weight: 162.235
• DSSTox Substance ID: DTXSID30708325
• Mol file: 92882-31-0.mol

Synonyms:(2-Methyl-3-phenylprop-2-en-1-yl)hydrazine;92882-31-0;DTXSID30708325

Chemical Property of (2-Methyl-3-phenylprop-2-enyl)hydrazine

Chemical Property:

• XLogP3: 1.8
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 162.115698455
• Heavy Atom Count: 12
• Complexity: 146

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=CC1=CC=CC=C1)CNN

Technology Process of (2-Methyl-3-phenylprop-2-enyl)hydrazine

There total 2 articles about (2-Methyl-3-phenylprop-2-enyl)hydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

<(Z)-2-methyl-3-phenyl-2-propenyl>amine (97294-57-0) → <(Z)-2-methyl-3-phenyl-2-propenyl>hydrazine (92882-31-0)

Guidance literature:

With hydroxylamine-O-sulfonic acid; In water; for 0.333333h;

DOI:10.1021/jm00148a011

Reference yield:

(Z)-2-methyl-3-phenyl-2-propenenitrile (26157-51-7) → <(Z)-2-methyl-3-phenyl-2-propenyl>hydrazine (92882-31-0)

Guidance literature:

Multi-step reaction with 2 steps

1: AlCl₃, LiAlH₄ / diethyl ether / 18 h / Ambient temperature

2: hydroxylamine-O-sulfonic acid / H₂O / 0.33 h

With lithium aluminium tetrahydride; aluminium trichloride; hydroxylamine-O-sulfonic acid; In diethyl ether; water;

DOI:10.1021/jm00148a011

Reference yield: 76.0%

2-oxo-propionic acid (127-17-3) + <(Z)-2-methyl-3-phenyl-2-propenyl>hydrazine (92882-31-0) → 2-[((E)-2-Methyl-3-phenyl-allyl)-hydrazono]-propionic acid (92836-23-2)

Guidance literature:

With sodium acetate; In water; for 2h;

DOI:10.1021/jm00148a011

upstream raw materials:

<(Z)-2-methyl-3-phenyl-2-propenyl>amine

(Z)-2-methyl-3-phenyl-2-propenenitrile

Downstream raw materials:

2-[((E)-2-Methyl-3-phenyl-allyl)-hydrazono]-propionic acid