4-phenylsulfanylbutylsulfanylbenzene

Base Information

• Chemical Name: 4-phenylsulfanylbutylsulfanylbenzene
• CAS No.: 5330-89-2
• Molecular Formula: C16H16ClNO3
• Molecular Weight: 274.451
• Mol file: 5330-89-2.mol

Synonyms:

Chemical Property of 4-phenylsulfanylbutylsulfanylbenzene

Chemical Property:

• Boiling Point: 408°Cat760mmHg
• Flash Point: 200.9°C
• Density: 1.12g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-phenylsulfanylbutylsulfanylbenzene

There total 12 articles about 4-phenylsulfanylbutylsulfanylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + thiophenol (108-98-5) → 1,4-bis-phenylsulfanyl-butane (5330-89-2)

Guidance literature:

tetrahydrofuran; With t-butyl bromide; 1-pentyl-3-methylimidazolium bromide; at 60 ℃;

thiophenol; With 1-pentyl-3-methylimidazolium bromide; at 60 ℃;

DOI:10.1002/adsc.200505122

Reference yield: 95.0%

1-chloro-4-(phenylthio)butane (14633-31-9) → 1,4-bis-phenylsulfanyl-butane (5330-89-2)

Guidance literature:

With aluminum oxide; at 120 ℃;

Reference yield: 87.0%

→ 1,4-bis-phenylsulfanyl-butane (5330-89-2)

Guidance literature:

In dichloromethane; acetonitrile; for 4h; Ambient temperature; Irradiation;

upstream raw materials:

1,4-dibromo-butane

sodium thiophenolate

1-chloro-4-(phenylthio)butane

thiophenol

Downstream raw materials:

[Au₂Cl₂(1,4-bis(phenylthio)butane)]

HgCl₂(C₆H₅S(CH₂)4SC₆H₅)

1,1,4,4-tetrakis(phenylthio)butane

Refernces

• 1、 Huang, Mingming,Hu, Jiefeng,Krummenacher, Ivo,Friedrich, Alexandra,Braunschweig, Holger,Westcott, Stephen A.,Radius, Udo,Marder, Todd B.. "Base-Mediated Radical Borylation of Alkyl Sulfones". supporting information. . Retrieved 2021/12/02.
• 2、 Bai, Shi-Qiang,Wong, Ivy Hoi Ka,Zhang, Nan,Lin Ke, Karen,Lin, Ming,Young, David James,Hor, T. S. Andy. "A new 3-D coordination polymer as a precursor for CuI-based thermoelectric composites". supporting information. p. 16292 - 16298. Retrieved 2018/11/30.