[(1-Methoxy-2-methylprop-2-en-1-yl)sulfanyl]benzene

Base Information

• Chemical Name: [(1-Methoxy-2-methylprop-2-en-1-yl)sulfanyl]benzene
• CAS No.: 93233-72-8
• Molecular Formula: C₁₁H₁₄OS
• Molecular Weight: 194.298
• DSSTox Substance ID: DTXSID20534014
• Mol file: 93233-72-8.mol

Synonyms:93233-72-8;[(1-Methoxy-2-methylprop-2-en-1-yl)sulfanyl]benzene;DTXSID20534014

Chemical Property of [(1-Methoxy-2-methylprop-2-en-1-yl)sulfanyl]benzene

Chemical Property:

• PSA: 34.53000
• LogP: 3.32730
• XLogP3: 3.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 194.07653624
• Heavy Atom Count: 13
• Complexity: 162

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(OC)SC1=CC=CC=C1

Technology Process of [(1-Methoxy-2-methylprop-2-en-1-yl)sulfanyl]benzene

There total 2 articles about [(1-Methoxy-2-methylprop-2-en-1-yl)sulfanyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-Methoxy-2-methyl-1-phenylsulfanyl-3-trimethylsilanyl-propan-2-ol (344437-72-5) → (1-Methoxy-2-methyl-allylsulfanyl)-benzene (93233-72-8)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydride; In tetrahydrofuran; Yield given; Ambient temperature;

DOI:10.1246/cl.1984.1259

Reference yield:

1-methoxy-1-phenylthiopropan-2-one (22198-58-9) → (1-Methoxy-2-methyl-allylsulfanyl)-benzene (93233-72-8)

Guidance literature:

Multi-step reaction with 2 steps

1: diethyl ether / 0 °C

2: NaH, HMPA / tetrahydrofuran / Ambient temperature

With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydride; In tetrahydrofuran; diethyl ether;

DOI:10.1246/cl.1984.1259

Reference yield:

(1-Methoxy-2-methyl-allylsulfanyl)-benzene (93233-72-8) → C11H13(2)HOS (95091-19-3)

Guidance literature:

With water-d2; lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; Yield given;

DOI:10.1016/S0040-4039(01)81719-6

upstream raw materials:

1-Methoxy-2-methyl-1-phenylsulfanyl-3-trimethylsilanyl-propan-2-ol

1-methoxy-1-phenylthiopropan-2-one

Downstream raw materials:

(1-Isopropenyl-1-methoxy-heptylsulfanyl)-benzene

C₁₁H₁₃⁽²⁾HOS

C₁₁H₁₃⁽²⁾HOS

2-((Z)-4-Methoxy-5-methyl-6-phenylsulfanyl-hex-4-enyloxy)-tetrahydro-pyran