NICKELSULFARSENIDE

Base Information

• Chemical Name: NICKELSULFARSENIDE
• CAS No.: 12255-10-6
• Molecular Formula: AsNiS
• Molecular Weight: 165.678
• Mol file: 12255-10-6.mol

Synonyms:NICKELSULPHARSENIDE

Chemical Property of NICKELSULFARSENIDE

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of NICKELSULFARSENIDE

There total 12 articles about NICKELSULFARSENIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

arsenic trisulfide + nickel (7440-02-0) → nickel(II) sulfide + gersdorffite (12255-10-6,12255-11-7)

Guidance literature:

In sodium hydroxide; Raney nickel;

Reference yield:

bis(O-butyldithiocarbonato)nickel(II) (52139-58-9) + arsenic(III) trioxide → gersdorffite (12255-10-6,12255-11-7)

Guidance literature:

In kerosene; in a stirred autoclave react. of metal complex and As-compd. in kerosine under H2 (650°F, 1000 psig, 2 h); filtn., washing with a suitable solvent, drying, anal. by X-ray diffraction;

DOI:10.1006/jssc.1994.1095

Reference yield:

arsenic + nickel(II) sulfide → gersdorffite (12255-10-6,12255-11-7)

Guidance literature:

In neat (no solvent, solid phase); mixing in at. ratio 1:1:1, sealing in evacuated tubes, placing in cold furnace, heating to 220°C, holding at that temp. for 2 h, heating to 400°C, annealing at that temp. for 24 h, heating to 690°C, annealing at that temp. for 20 d; slowly cooling to room temp.;

DOI:10.1006/jssc.2001.9342

upstream raw materials:

nickel

bis(O-butyldithiocarbonato)nickel(II)

sulfur

bis(N,N-dibutyldithiocarbamato-S,S')nickel(II)

Refernces

• 1、 Muldagalieva,Chunaeva,Isabaev. "Synthesis of Iron, Cobalt, and Nickel Sulfoarsenides". . p. 1726 - 1727. Retrieved 2008/10/08.