Hydroxytriphenylsilane

Base Information

• Chemical Name: Hydroxytriphenylsilane
• CAS No.: 16527-35-8
• Molecular Formula: C18H16 O Si . Na
• Molecular Weight: 298.392
• Hs Code.: 2931900090
• Mol file: 16527-35-8.mol

Synonyms:Silanol,triphenyl-, sodium deriv. (6CI); Silanol, triphenyl-, sodium salt (9CI);Sodium, (triphenylsiloxy)- (7CI); Sodium triphenylsilanolate

Chemical Property of Hydroxytriphenylsilane

Chemical Property:

• PSA: 20.23000
• LogP: 1.64580

Purity/Quality:

SodiumTriphenylsilanolate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Hydroxytriphenylsilane

There total 4 articles about Hydroxytriphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

triphenylhydroxysilane (791-31-1) → sodium triphenylsilanolate (16527-35-8)

Guidance literature:

With sodium hydroxide; In methanol; isopropyl alcohol; toluene; heating of (C6H5)3SiOH and NaOH in isopropanol-methanol and toluene at 115°C;;

DOI:10.1021/ja01118a042

Reference yield: 81.0%

hexaphenyldisiloxanne (1829-40-9) → sodium triphenylsilanolate (16527-35-8)

Guidance literature:

With sodium hydroxide; In methanol; isopropyl alcohol; toluene; heating of ((C6H5)3Si)2O and NaOH in isopropanol-methanol and toluene at 115°C;;

DOI:10.1021/ja01118a042

Reference yield:

HSiPh3 (789-25-3) → sodium triphenylsilanolate (16527-35-8)

Guidance literature:

Multi-step reaction with 2 steps

1: KOH / ethanol

2: NaOH / methanol; toluene; isopropyl alcohol

With KOH; NaOH; In methanol; ethanol; isopropyl alcohol; toluene;

upstream raw materials:

hexaphenyldisiloxanne

triphenylhydroxysilane

HSiPh₃

Downstream raw materials:

3-methyl-1,1,1,5,5,5-hexaphenyl-trisiloxane

3-chloro-3-methyl-1,1,1-triphenyl-disiloxane

hexaphenyldisiloxanne

bis(N-diphenylphosphoryl-P,P-diphenylphosphinimidato-κ(2)O,O')-oxovanadium(IV)