2-Propanone, 1,1,3,3-tetraphenyl-, ion(2-), dilithium

Base Information

Chemical Name:2-Propanone, 1,1,3,3-tetraphenyl-, ion(2-), dilithium
CAS No.:94234-97-6
Molecular Formula:C27H20O.2Li
Molecular Weight:376.353
Hs Code.:

Synonyms:

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Chemical Property of 2-Propanone, 1,1,3,3-tetraphenyl-, ion(2-), dilithium

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Technology Process of 2-Propanone, 1,1,3,3-tetraphenyl-, ion(2-), dilithium

There total 4 articles about 2-Propanone, 1,1,3,3-tetraphenyl-, ion(2-), dilithium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 7476-11-1
1,1,3,3-tetraphenylpropane-2-one

: 94234-97-6
C₂₇H₂₂O^(2-)*2Li⁽¹⁺⁾

Guidance literature:: With n-butyllithium; In tetrahydrofuran; at 34 ℃; for 0.166667h;
DOI:10.1021/ja00289a028

Reference yield:

: 111975-70-3
<1,2-13C>-1,1,3,3-tetraphenylacetone

: 94234-97-6
1,1,3,3-tetraphenylacetone dianion lithium salt

Guidance literature:: With n-butyllithium; In tetrahydrofuran; tetrahydrofuran-d8; hexane; 1.) -10 deg C, 15 min; 2.) room temp., 30 min;
DOI:10.1021/ja00211a029

Reference yield:

: 96165-51-4
<13C2>-diphenylacetic acid

: 94234-97-6
1,1,3,3-tetraphenylacetone dianion lithium salt

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / thionyl chloride / 14 h

2: 1.) n-BuLi / 1.) THF, hexane, 1.5 h; 2.) THF, hexane, 0 deg C, 2 h, then allowed to warm to room temp.

3: n-butyllithium / tetrahydrofuran-d8; hexane; tetrahydrofuran / 1.) -10 deg C, 15 min; 2.) room temp., 30 min

With n-butyllithium; thionyl chloride; In tetrahydrofuran; tetrahydrofuran-d8; hexane;
DOI:10.1021/ja00211a029