Cyclohexanone, 3-[(dimethyl-2-propenylsilyl)methyl]-3,5,5-trimethyl-

Base Information

Chemical Name:Cyclohexanone, 3-[(dimethyl-2-propenylsilyl)methyl]-3,5,5-trimethyl-
CAS No.:94616-88-3
Molecular Formula:C₁₅H₂₈OSi
Molecular Weight:252.472
Hs Code.:
DSSTox Substance ID:DTXSID10433845

Synonyms:Cyclohexanone, 3-[(dimethyl-2-propenylsilyl)methyl]-3,5,5-trimethyl-;94616-88-3;DTXSID10433845

Suppliers and Price of Cyclohexanone, 3-[(dimethyl-2-propenylsilyl)methyl]-3,5,5-trimethyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Cyclohexanone, 3-[(dimethyl-2-propenylsilyl)methyl]-3,5,5-trimethyl-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:4
Exact Mass:252.190942047
Heavy Atom Count:17
Complexity:317

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(CC(=O)CC(C1)(C)C[Si](C)(C)CC=C)C

Technology Process of Cyclohexanone, 3-[(dimethyl-2-propenylsilyl)methyl]-3,5,5-trimethyl-

There total 1 articles about Cyclohexanone, 3-[(dimethyl-2-propenylsilyl)methyl]-3,5,5-trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 78-59-1
3,5,5-Trimethylcyclohex-2-en-1-one

: 49759-12-8
(allyldimethylsilyl)methylmagnesium chloride

: 94616-88-3
3-(Allyl-dimethyl-silanylmethyl)-3,5,5-trimethyl-cyclohexanone

Guidance literature:: copper(l) iodide; In diethyl ether; for 1h; Ambient temperature; addition at 0 deg C;
DOI:10.1016/S0040-4039(01)81408-8

Reference yield:

: 94616-88-3
3-(Allyl-dimethyl-silanylmethyl)-3,5,5-trimethyl-cyclohexanone

: 94616-89-4
3-(Fluoro-dimethyl-silanylmethyl)-3,5,5-trimethyl-cyclohexanone

Guidance literature:: With potassium hydrogen bifluoride; trifluoroacetic acid; In chloroform; at 50 ℃; for 3h;
DOI:10.1016/S0040-4039(01)81408-8

Reference yield:

: 94616-88-3
3-(Allyl-dimethyl-silanylmethyl)-3,5,5-trimethyl-cyclohexanone

: 94616-90-7
3-hydroxymethyl-3,5,5-trimethylcyclohexanone

Guidance literature:: Multi-step reaction with 2 steps

1: KHF₂, CF₃COOH / CHCl₃ / 3 h / 50 °C

2: 30percent H₂O₂, NaHCO₃ / methanol; tetrahydrofuran / 10 h / Heating

With potassium hydrogen bifluoride; dihydrogen peroxide; sodium hydrogencarbonate; trifluoroacetic acid; In tetrahydrofuran; methanol; chloroform;
DOI:10.1016/S0040-4039(01)81408-8