(2R)-2-[(1R)-1-(furan-3-yl)-2-oxopropyl]-2,6,6-trimethylcyclohexanone

Base Information

Chemical Name:(2R)-2-[(1R)-1-(furan-3-yl)-2-oxopropyl]-2,6,6-trimethylcyclohexanone
CAS No.:124070-94-6
Molecular Formula:C16H22 O3
Molecular Weight:262.3441
Hs Code.:
Mol file:124070-94-6.mol

Synonyms:Cyclohexanone,2-[1-(3-furanyl)-2-oxopropyl]-2,6,6-trimethyl-, (R*,R*)- (9CI); Cyclohexanone,2-[1-(3-furanyl)-2-oxopropyl]-2,6,6-trimethyl-, (R*,R*)-(?à)-

Suppliers and Price of (2R)-2-[(1R)-1-(furan-3-yl)-2-oxopropyl]-2,6,6-trimethylcyclohexanone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of (2R)-2-[(1R)-1-(furan-3-yl)-2-oxopropyl]-2,6,6-trimethylcyclohexanone

Chemical Property:

Vapor Pressure:5.1E-05mmHg at 25°C
Boiling Point:348.2°Cat760mmHg
Flash Point:163.4°C
Density:1.041g/cm³

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (2R)-2-[(1R)-1-(furan-3-yl)-2-oxopropyl]-2,6,6-trimethylcyclohexanone

There total 4 articles about (2R)-2-[(1R)-1-(furan-3-yl)-2-oxopropyl]-2,6,6-trimethylcyclohexanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 83999-44-4
2,6,6-trimethyl-1-trimethylsilyloxycyclohexene

: 124070-88-8,860003-90-3
(E)-1-(3-furyl)-2-nitro-1-propene

: 124070-94-6
(1'RS,2SR)-2,6,6-trimethyl-2-<1'-(3-furyl)-2-oxopropyl>cyclohexanone

: 124070-93-5
(4RS,4aSR)-4-(3-furyl)-3,4a,8,8-tetramethyl-8a-(trimethylsiloxy)-4a,5,6,7,8,8a-hexahydro-4H-1,2-benzoxazine N-oxide

Guidance literature:: With titanium tetrachloride; In dichloromethane; at -78 ℃; for 0.25h;
DOI:10.1021/jo00291a048

Reference yield:

: 124070-93-5
(4RS,4aSR)-4-(3-furyl)-3,4a,8,8-tetramethyl-8a-(trimethylsiloxy)-4a,5,6,7,8,8a-hexahydro-4H-1,2-benzoxazine N-oxide

: 124070-94-6
(1'RS,2SR)-2,6,6-trimethyl-2-<1'-(3-furyl)-2-oxopropyl>cyclohexanone

Guidance literature:: With titanium(III) chloride; In tetrahydrofuran; for 10h; Ambient temperature;
DOI:10.1021/jo00291a048

Reference yield:

: 124070-88-8,860003-90-3
(E)-1-(3-furyl)-2-nitro-1-propene

: 124070-94-6
(1'RS,2SR)-2,6,6-trimethyl-2-<1'-(3-furyl)-2-oxopropyl>cyclohexanone

Guidance literature:: Multi-step reaction with 2 steps

1: 15 percent / TiCl₄ / CH₂Cl₂ / 0.25 h / -78 °C

2: aq. TiCl₃ / tetrahydrofuran / 10 h / Ambient temperature

With titanium(III) chloride; titanium tetrachloride; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00291a048