Tributyl[(phenylacetyl)oxy]stannane

Base Information

• Chemical Name: Tributyl[(phenylacetyl)oxy]stannane
• CAS No.: 94763-25-4
• Molecular Formula: C20H34O2Sn
• Molecular Weight: 425.199
• DSSTox Substance ID: DTXSID80587167
• Wikidata: Q82479499
• Mol file: 94763-25-4.mol

Synonyms:Tributyl[(phenylacetyl)oxy]stannane;94763-25-4;DTXSID80587167

Chemical Property of Tributyl[(phenylacetyl)oxy]stannane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 13
• Exact Mass: 426.158083
• Heavy Atom Count: 23
• Complexity: 289

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[Sn](CCCC)(CCCC)OC(=O)CC1=CC=CC=C1

Technology Process of Tributyl[(phenylacetyl)oxy]stannane

There total 10 articles about Tributyl[(phenylacetyl)oxy]stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

phenylacetic acid (103-82-2) + tributyltin chloride (1461-22-9) → tri-n-butylstannyl phenylacetate (94763-25-4)

Guidance literature:

in the presence of alkali hydroxyde;

DOI:10.1016/S0022-328X(00)92407-0

Reference yield: 90.0%

phenylacetic acid (103-82-2) + tri-n-butyltin acetate → tri-n-butylstannyl phenylacetate (94763-25-4)

Guidance literature:

In ethanol; toluene; byproducts: H2O; refluxing equimolar amts. for 4-6 h (in PhMe/EtOH=4:1) with azeotropic distn. off of H2O; evapn., recrystn. (CH2Cl2/hexane);

DOI:10.1016/S0022-328X(96)06686-7

Reference yield: 83.0%

phenylacetic acid (103-82-2) + bis(tri-n-butyltin)oxide (56-35-9) → tri-n-butylstannyl phenylacetate (94763-25-4)

Guidance literature:

byproducts: H2O;

upstream raw materials:

phenylacetic acid

bis(tri-n-butyltin)oxide

benzyl alcohol

tributyltin chloride

Downstream raw materials:

2-(4-chlorophenyl)-2-oxoethyl 2-phenylacetate

2-(4-bromophenyl)-2-oxoethyl 2-phenylacetate

m-Nitrophenacyl phenylacetate

2-oxo-2-phenylethyl 2-phenylacetate