Phosphine, [2-[bis(3-fluorophenyl)phosphino]ethyl]diphenyl-

Base Information

Chemical Name:Phosphine, [2-[bis(3-fluorophenyl)phosphino]ethyl]diphenyl-
CAS No.:94940-44-0
Molecular Formula:C26H22F2P2
Molecular Weight:434.405
Hs Code.:
DSSTox Substance ID:DTXSID10461103
Nikkaji Number:J1.347.207F
Wikidata:Q82285350

Synonyms:94940-44-0;Phosphine, [2-[bis(3-fluorophenyl)phosphino]ethyl]diphenyl-;DTXSID10461103

Suppliers and Price of Phosphine, [2-[bis(3-fluorophenyl)phosphino]ethyl]diphenyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Phosphine, [2-[bis(3-fluorophenyl)phosphino]ethyl]diphenyl-

Chemical Property:

XLogP3:6.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:7
Exact Mass:434.11648102
Heavy Atom Count:30
Complexity:449

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(CCP(C2=CC=CC(=C2)F)C3=CC=CC(=C3)F)C4=CC=CC=C4

Technology Process of Phosphine, [2-[bis(3-fluorophenyl)phosphino]ethyl]diphenyl-

There total 2 articles about Phosphine, [2-[bis(3-fluorophenyl)phosphino]ethyl]diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: bis(3-fluorophenyl)phosphorus

: 2155-96-6
Diphenylvinylphosphine

: 94940-44-0
1-diphenylphosphino-2-bis(m-fluorophenyl)phosphinoethane

Guidance literature:: With potassium tert-butylate; In tetrahydrofuran; for 6h; Heating;
DOI:10.1016/0022-328X(84)80627-0

Reference yield:

: 94940-34-8
3,3’-difluorodiphenylphosphine oxide

: 94940-44-0
1-diphenylphosphino-2-bis(m-fluorophenyl)phosphinoethane

Guidance literature:: Multi-step reaction with 2 steps

1: LiAlH₄ / diethyl ether

2: 78 percent / t-BuOK / tetrahydrofuran / 6 h / Heating

With lithium aluminium tetrahydride; potassium tert-butylate; In tetrahydrofuran; diethyl ether;
DOI:10.1016/0022-328X(84)80627-0

Reference yield: 90.0%

: dichlorotetrakis(dimethylsulfoxide)ruthenium(II)

: 94940-44-0
1-diphenylphosphino-2-bis(m-fluorophenyl)phosphinoethane

: 111487-57-1
dichlorobis[1-diphenylphosphino-2-bis(m-fluorophenyl)phosphinoethane]ruthenium(II)

Guidance literature:: In ethanol; Ru complex and the ligand are refluxed in EtOH for 6 h; soln. is cooled to room temp., solvent is removed in vac., recrystn. from CHCl3/EtOH; elem. anal.;
DOI:10.1016/S0020-1693(00)87902-5