cinatrin C3

Base Information

• Chemical Name: cinatrin C3
• CAS No.: 136266-37-0
• Molecular Formula: C₁₈H₃₀O₈
• Molecular Weight: 374.431
• Mol file: 136266-37-0.mol

Synonyms:Cinatrin C3

Chemical Property of cinatrin C3

Chemical Property:

• Vapor Pressure: 1.68E-15mmHg at 25°C
• Boiling Point: 572.7°Cat760mmHg
• Flash Point: 199.3°C
• PSA: 130.36000
• Density: 1.226g/cm³
• LogP: 2.67090

Purity/Quality:

95% ^*data from raw suppliers

CINATRIN C3 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of cinatrin C3

There total 22 articles about cinatrin C3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

cinatrin C1 dimethyl ester (136266-39-2) → cinatrin C1 (136266-35-8) + cinatrin C3 (136266-37-0)

Guidance literature:

cinatrin C₁ dimethyl ester; With sodium hydroxide; In tetrahydrofuran; at 40 ℃; for 22h;

With hydrogenchloride; In tetrahydrofuran; at 20 - 40 ℃; for 4.5h; Further stages.;

DOI:10.1039/b308028e

Reference yield: 22.0%

di-tert-butyl-(2S,3R)-2((1S)-1-carboxy-1-hydroxydodecyl)-1,4-dioxaspiro[4.4]nonane-2,3-dicarboxylate → (+)-cinatrin C1 (136266-35-8) + (-)-cinatrin C3 (136266-37-0)

Guidance literature:

In dichloromethane; water; trifluoroacetic acid; for 12h; Ambient temperature;

DOI:10.1016/S0040-4020(97)90390-2

Reference yield:

rac-(3R,4S,5S)-3,4-dihydroxy-3-dodecyl-4,5-bis(methoxycarbonyl)tetrahydro-2-furanone → rac-(3S,4S,5R)-3,4-dihydroxy-5-dodecyl-4,5-dicarboxytetrahydro-2-furanone (136266-35-8) + rac-(3R,4S,5S)-3,4-dihydroxy-3-dodecyl-4,5-dicarboxytetrahydro-2-furanone (136266-37-0)

Guidance literature:

rac-(3R,4S,5S)-3,4-dihydroxy-3-dodecyl-4,5-bis(methoxycarbonyl)tetrahydro-2-furanone; With water; lithium hydroxide; In tetrahydrofuran; at 20 ℃; for 2h;

With hydrogenchloride; In water;

upstream raw materials:

cinatrin C₁ dimethyl ester

(2R,3S,4S,5S)-3,4-Bis-benzyloxy-2-((E)-dodec-2-enyl)-5-methoxy-tetrahydro-furan-2-carboxylic acid methyl ester

methyl methyl-4-C-dodecanyl-D-erythro-3-pentulofuranosiduronate

methyl methyl-4-C-dodecanyl-β-L-xylofuranosiduronate