Manganese, dibromo(phenyldipropylphosphine)bis(tetrahydrofuran)-

Base Information

• Chemical Name: Manganese, dibromo(phenyldipropylphosphine)bis(tetrahydrofuran)-
• CAS No.: 96120-52-4
• Molecular Formula: C₂₀H₃₅Br₂MnO₂P
• Molecular Weight: 553.216
• Mol file: 96120-52-4.mol

Synonyms:

Chemical Property of Manganese, dibromo(phenyldipropylphosphine)bis(tetrahydrofuran)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Manganese, dibromo(phenyldipropylphosphine)bis(tetrahydrofuran)-

There total 1 articles about Manganese, dibromo(phenyldipropylphosphine)bis(tetrahydrofuran)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

manganese(II) bromide (13446-03-2) → dibromodipropylphenylphosphinebis(tetrahydrofuran)manganese(II) (96120-52-4)

Guidance literature:

With P(C₆H₅)(C₃H₇)2, THF; In neat (no solvent); the mixt. of MnBr2, phosphine and THF was stirred for 10 d under Ar; THF was removed in vac., pentan was added, the mixt. was stirred for 1 h, ppt. was filtered, dried in vac. for 6 h;

DOI:10.1016/S0020-1693(00)87987-6

Reference yield:

dibromodipropylphenylphosphinebis(tetrahydrofuran)manganese(II) (96120-52-4) → [(Mn(dipropylphenylphosphine)Br2(tetrahydrofuran)2)2(μ-CS2)]

Guidance literature:

With CS₂; In diethyl ether; the soln. of Mn complex was refluxed under Ar, excess CS2 was added, the mixt. was refluxed for 48 h; the mixt. was cooled to 25°C, filtered, ppt. was washed with ether, dried in vac. for 6 h at 25°C, elem. anal.;

DOI:10.1016/S0020-1693(00)87987-6

upstream raw materials:

manganese(II) bromide