Germane, (3-chloro-1-butynyl)triphenyl-

Base Information

• Chemical Name: Germane, (3-chloro-1-butynyl)triphenyl-
• CAS No.: 96254-38-5
• Molecular Formula: C₂₂H₁₉ClGe
• Molecular Weight: 391.436
• Mol file: 96254-38-5.mol

Synonyms:

Chemical Property of Germane, (3-chloro-1-butynyl)triphenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Germane, (3-chloro-1-butynyl)triphenyl-

There total 1 articles about Germane, (3-chloro-1-butynyl)triphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-chloro-but-1-yne (21020-24-6) + chlorotriphenylgermane (1626-24-0) → (C6H5)3GeCCCH(Cl)CH3 (96254-38-5)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; BuLi in hexane was cautiously added under N2 at -100°C to a stirred soln. of propargylic chloride in THF, after 10 min Ph3GeCl was added, mixt. was stirred at -60°C for 0.5 h, allowed to warm to room temp.; mixt. was poured into satd. aq. NH4Cl, extd. with 1:1 ether-pentane, combined exts. were washed with water, dried over MgSO4, evapd. in vacuo;

DOI:10.1016/0022-328X(84)80703-2

upstream raw materials:

3-chloro-but-1-yne

chlorotriphenylgermane

Refernces